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Solid Solutions PdTe1– xBix (x < 0.8) with the NiAs Structure in the Pd–Bi–Te System

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Three solid solutions in the Pd–Bi–Te system were obtained by high-temperature ampoule synthesis from the elements at 700°C. The crystal structures of the solid solutions were determined using powder diffraction data by the full-profile Rietveld method. The solid solutions PdTe0.33Bi0.67 (a = 4.19816(8) Å, c = 5.6861(1) Å), PdTe0.5Bi0.5 (a = 4.18888(9) Å, c = 5.6778(1) Å), and PdTe0.67Bi0.33 (a = 4.17796(8) Å, c = 5.6733(1) Å) belong to the PdTe1 – xBix series: the structures of compounds are based on the statistical substitution of Bi atoms for Te atoms in the PdTe structure (NiAs type, hexagonal system, space group P63/mmc). The concentration limit for substitution in the PdTe1 – xBix series of solid solutions is in the 0.67 < x < 0.8 range. Band structure calculations demonstrate the metallic nature for all compounds and similar electronic structures for PdTe, PdTe1– xBix, and PdBi.

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ACKNOWLEDGMENTS

The research was carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University.

Funding

This work was supported by the Russian Science Foundation (project no. 17-73-10492).

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Authors and Affiliations

  1. Lomonosov Moscow State University, 119991, Moscow, Russia

    E. Yu. Zakharova, A. Yu. Makhaneva, S. M. Kazakov & A. N. Kuznetsov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. N. Kuznetsov

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  1. E. Yu. Zakharova
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  2. A. Yu. Makhaneva
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  3. S. M. Kazakov
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  4. A. N. Kuznetsov
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Correspondence to E. Yu. Zakharova.

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Translated by Z. Svitanko

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Zakharova, E.Y., Makhaneva, A.Y., Kazakov, S.M. et al. Solid Solutions PdTe1– xBix (x < 0.8) with the NiAs Structure in the Pd–Bi–Te System. Russ. J. Inorg. Chem. 64, 1486–1493 (2019). https://doi.org/10.1134/S0036023619120192

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