Skip to main content
SpringerLink
Log in

Synthesis and ionic conductivity of silver magnesium zirconium molybdates

  • Published:
Inorganic Materials Aims and scope

Abstract

The silver magnesium zirconium molybdate Ag4Mg2Zr(MoO4), undoped and aliovalently doped with yttrium and aluminum, has been characterized by impedance spectroscopy, X-ray diffraction, and IR spectroscopy. The materials studied possess relatively high ionic conductivity at temperatures above 550 K. Partial yttrium substitution on the zirconium site ensures an increase in ionic conductivity almost throughout the temperature range studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kuzyk, B.N., Rossiya i mir v XXI veke (Russia and the World in the 21st Century), Moscow: Inst. Ekonomicheskikh Strategii, 2005.

    Google Scholar 

  2. Kalinin, V.B. and Stefanovich, S.Yu., Cation Mobility in Orthophosphates, Itogi Nauki Tekh., Ser.: Khim. Tverd. Tela, vol. 8, 1992.

  3. Khobrakova, V.A., Morozov, S.S., Khasanov, G.D., et al., New Molybdenum Oxides Ag4M2Zr(MoO4)6 (M = Mg, Mn, Co, Zn) with a Channel-Like Structure, Solid State Sci., 2005, vol. 7, no. 11, pp. 1397–1405.

    Article  CAS  Google Scholar 

  4. Bokshtein, B.S. and Yaroslavtsev, A.B., Diffuziya atomov i ionov v tverdykh telakh (Diffusion of Atoms and Ions in Solids), Moscow: Mosk. Inst. Stali i Splavov, 2005.

    Google Scholar 

  5. Subramanian, M.A., Roberts, B.D., and Clearfield, A., On the Proton Conductor (H3O)Zr2(PO4)3, Mater. Res. Bull., 1984, vol. 19, no. 11, pp. 1471–1478.

    Article  CAS  Google Scholar 

  6. Stenina, I.A., Voropaeva, E.Yu., Brueva, T.R., et al., Effect of Heat Treatment on the Morphology and Microstructure of Hydrous Zirconium Oxide Precipitated from Chloride Solutions, Zh. Neorg. Khim., 2008, vol. 53, no. 6, pp. 912–918.

    CAS  Google Scholar 

  7. Ivanov-Schitz, A.K. and Murin, I.V., Ionika tverdogo tela (Solid-State Ionics), St. Petersburg: S.-Peterb. Gos. Univ., 2000, vol. 1.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. A. Il’ina, I. A. Stenina, G. V. Lysanova & A. B. Yaroslavtsev

Authors
  1. A. A. Il’ina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. A. Stenina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. V. Lysanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. B. Yaroslavtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. B. Yaroslavtsev.

Additional information

Original Russian Text © A.A. Il’ina, I.A. Stenina, G.V. Lysanova, A.B. Yaroslavtsev, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 4, pp. 487–491.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Il’ina, A.A., Stenina, I.A., Lysanova, G.V. et al. Synthesis and ionic conductivity of silver magnesium zirconium molybdates. Inorg Mater 45, 436–439 (2009). https://doi.org/10.1134/S0020168509040207

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168509040207

Keywords

Search

Navigation