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Rare-earth-doped PbTiO3-PbZrO3 solid solutions

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Abstract

(Pb1 − x Ln x )(Zr0.53Ti0.47)O3 and (Pb1 − x Ln x )(Zr0.65Ti0.35)O3 (x = 0.02, 0.06; Ln = La, Pr, Gd, Yb) solid solutions have been prepared by modified solid-state synthesis using organic-ligand precursors. The solid solutions have been characterized by thermal analysis, IR spectroscopy, x-ray powder diffraction, and atomic force microscopy. All of them have a rhombohedrally distorted perovskite structure (sp. gr. R3c).

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References

  1. He, Z. and Ma, J., Constitutive Modeling of the Densification of PZT Ceramics, J. Phys. Chem. Solids, 2003, vol. 64, pp. 177–183.

    Article  CAS  Google Scholar 

  2. Soares, M.R., Senos, A.M.R., and Mantas, P.Q., Phase Coexistence Region and Dielectric Properties of PZT Ceramics, J. Eur. Ceram. Soc., 2000, vol. 20, pp. 321–334.

    Article  CAS  Google Scholar 

  3. Yimnirun, R., Wongsaenmai, S., Ananta, S., and Laosiritaworn, Y., Stress-Dependent Scaling Behavior of Dynamic Hysteresis in Bulk Soft Ferroelectric Ceramic, Appl. Phys. Lett., 2006, vol. 89, pp. 242 901–242 903.

    Google Scholar 

  4. Kozielski, L., Lisinska-Czekaj, A., and Czekaj, D., Graded PZT Ceramics for Piezoelectric Transformers, Prog. Solid State Chem., 2007, vol. 35, nos. 2–4, pp. 521–530.

    Article  CAS  Google Scholar 

  5. Rende, D., Schwarz, K., Rabe, U., et al., Combinatorial Synthesis of Thin Mixed Oxide Films and Automated Study of Their Piezoelectric Properties, Prog. Solid State Chem., 2007, vol. 35, nos. 2–4, pp. 361–366.

    Article  CAS  Google Scholar 

  6. Park, H., Jung, J., Min, D.-Ki., et al., Scanning Resistive Probe Microscopy: Imaging Ferroelectric Domains, Appl. Phys. Lett., 2004, vol. 84, no. 10, pp. 1734–1736.

    Article  CAS  Google Scholar 

  7. Efimov, V.V., Efimova, E.A., Iakoubovskii, K., et al., EXAFS, x-Ray Diffraction, and Raman Studies of (Pb1 − x Lax)(Zr0.65Ti0.35)O3 (x = 0.04 and 0.09) Ceramics Irradiated by High-Current Pulsed Electron Beam, J. Phys. Chem. Solids, 2006, vol. 67, pp. 2007–2012.

    Article  CAS  Google Scholar 

  8. Roy, S., Bysakh, S., Goswami, M.L.N., et al., Single-Step Synthesis of Ultrafine PLZT from Polymer Gel Precursor: Synthesis, Consolidation, and Dielectric Properties, Chem. Mater., 2007, vol. 19, no. 10, pp. 2622–2629.

    Article  CAS  Google Scholar 

  9. Weissberger, A., Proskauer, E.S., Riddick, J.A., and Toops, E.E., Jr., Organic Solvents: Physical Properties and Methods of Purification, New York: Interscience, 1955, 2nd ed.

    Google Scholar 

  10. Handbuch der pr“aparativen anorganischen Chemie, von Brauer, G., Ed., Stuttgart: Ferdinand Enke, 1978, 3rd ed. Translated under the title Rukovodstvo po neorganicheskomu sintezu, Moscow: Mir, 1985, vol. 4, p. 1487.

    Google Scholar 

  11. Shapiro, S.A. and Shapiro, M.A., Analiticheskaya khimiya (Analytical Chemistry), Moscow: Vysshaya Shkola, 1963.

    Google Scholar 

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Authors and Affiliations

  1. Karpov Institute of Physical Chemistry (Russian State Scientific Center), ul. Vorontsovo pole 10, Moscow, 105064, Russia

    S. K. Korchagina, L. F. Rybakova, O. L. Parkhomenko, N. V. Sadovskaya & A. A. Mikhailyuk

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  1. S. K. Korchagina
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  2. L. F. Rybakova
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  3. O. L. Parkhomenko
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  4. N. V. Sadovskaya
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  5. A. A. Mikhailyuk
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Correspondence to S. K. Korchagina.

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Original Russian Text © S.K. Korchagina, L.F. Rybakova, O.L. Parkhomenko, N.V. Sadovskaya, A.A. Mikhailyuk, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 3, pp. 330–333.

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Korchagina, S.K., Rybakova, L.F., Parkhomenko, O.L. et al. Rare-earth-doped PbTiO3-PbZrO3 solid solutions. Inorg Mater 45, 287–290 (2009). https://doi.org/10.1134/S0020168509030133

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  • DOI: https://doi.org/10.1134/S0020168509030133

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