Abstract
O2, Cl2, and SO2 chemisorption on the surface of nanocrystalline In2O3 doped with antimony (0.2 and 2.7 at %) has been studied at temperatures from 22 to 200°C. The results indicate that antimony prevents the formation of nonconducting indium chlorides on the surface of nanocrystalline In2O3 during Cl2 chemisorption. The logarithm of the conductivity of Sb-doped In2O3 is a nearly linear function of the surface coverage with chlorine, which makes it a candidate chlorine-sensing material. At the same time, antimony doping reduces the SO2 response of In2O3.
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Original Russian Text © M.V. Vinokurova, L.E. Derlyukova, A.A. Vinokurov, 2007, published in Neorganicheskie Materialy, 2007, Vol. 43, No. 10, pp. 1211–1218.
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Vinokurova, M.V., Derlyukova, L.E. & Vinokurov, A.A. Sorptive properties of antimony-doped In2O3 . Inorg Mater 43, 1085–1092 (2007). https://doi.org/10.1134/S0020168507100111
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DOI: https://doi.org/10.1134/S0020168507100111