Abstract
Carbon nanotubes (CNTs) were synthesized on ball-milled Fe2O3 coated copper sheets by the catalytic decomposition of ethanol vapor at 650°C. TEM, SEM, and EDX revealed the presence of 30–50 nm diameter multiwalled carbon nanotubes with catalytic particles at their tips. CNTs, α-Fe, and Fe3C were detected by XRD. Raman and TG analyses show that the product is CNTs with less than 10 wt % residues. The carbon yield was the maximum at 354 wt %.
Similar content being viewed by others
References
Iijima, S., Helical Microtubules of Graphitic Carbon, Nature, 1991, vol. 354, pp. 56–58.
Journet, C., Maser, W.K., Bernier, P., et al., Large-Scale Production of Single-Walled Carbon Nanotubes by the Electric-Arc Technique, Nature, 1997, vol. 388, pp. 756–758.
Park, J.B., Choi, G.S., Cho, Y.S., et al., Characterization of Fe-Catalyzed Carbon Nanotubes Grown by Thermal Chemical Vapor Deposition, J. Cryst. Growth, 2002, vol. 244, pp. 211–217.
Guo, T., Nikolaev, P., Thess, A., et al., Catalytic Growth of Single-Walled Nanotubes by Laser Vaporization, Chem. Phys. Lett., 1995, vol. 243, pp. 49–54.
Gulino, G., Vieira, R., Amadou, J., et al., C2H6 as an Active Carbon Source for a Large Scale Synthesis of Carbon Nanotubes by Chemical Vapour Deposition, Appl. Catal., A, 2005, vol. 279, pp. 89–97.
Li, Y., Zhang, X.B., Tao, X.Y., et al., Mass Production of High-Quality Multi-walled Carbon Nanotube Bundles on a Ni/Mo/MgO Catalyst, Carbon, 2005, vol. 43, pp. 295–301.
Singh, C., Shaffer, M.S.P., Koziol, K.K.K., et al., Towards the Production of Large-Scale Aligned Carbon Nanotubes, Chem. Phys. Lett., 2003 vol. 372, pp. 860–865.
Hou, H., Schaper, A.K., Jun, Z., et al., Large-Scale Synthesis of Aligned Carbon Nanotubes Using FeCl3 as Floating Catalyst Precursor, Chem. Mater., 2003, vol. 15, pp. 580–585.
Maruyama, S., Kojima, R., Miyauchi, Y., et al., Low-Temperature Synthesis of High-Purity Single-Walled Carbon Nanotubes from Alcohol, Chem. Phys. Lett., 2002, vol. 360, pp. 229–234.
Okazaki, T. and Shinohara, H., Synthesis and Characterization of Single-Wall Carbon Nanotubes by Hot-Filament Assisted Chemical Vapor Deposition, Chem. Phys. Lett., 2003, vol. 376, pp. 606–611.
Chiashi, S., Murmaki, Y., Miyauchi, Y., and Maruyama, S., Cold Wall CVD Generation of Single-Walled Carbon Nanotubes and In Situ Raman Scattering Measurements of the Growth Stage, Chem. Phys. Lett., 2004, vol. 386, pp. 89–94.
Okamoto, A. and Shinohara, H., Control of Diameter Distribution of Single-Walled Carbon Nanotubes Using the Zeolite-CCVD Method at Atmospheric Pressure, Carbon, 2005, vol. 43, pp. 431–436.
Emmenegger, C., Mauron, P., Zuttel, A., et al., Carbon Nanotube Synthesized on Metallic Substrates, Appl. Surf. Sci., 2000, vols. 162–163, pp. 452–456.
Mauron, P., Emmenegger, C., Zuttel, A., et al., Synthesis of Oriented Nanotube Films by Chemical Vapor Deposition, Carbon, 2002, vol. 40, pp. 1339–1344.
Hongo, H., Nihey, F., Ichihashi, T., et al., Support Materials Based on Converted Aluminum Films for Chemical Vapor Deposition Growth of Single-Wall Carbon Nanotubes, Chem. Phys. Lett., 2003, vol. 380, pp. 158–164.
Emmenegger, C., Bonard, J.M., Mauron, P., et al., Synthesis of Carbon Nanotubes over Fe Catalyst on Aluminium and Suggested Growth Mechanism, Carbon, 2003, vol. 41, pp. 539–547.
Volkova, E.G., Volkov, A.Y., Murzakaev, A.M., et al., Carbon Nanostructures Synthesized at Metallic Foils, Phys. Met. Metallogr., 2003, vol. 95, pp. 342–345.
Powder Diffraction File, Newtown Square: ICDD, 2001.
Author information
Authors and Affiliations
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Singjai, P., Thongtem, T., Kumfu, S. et al. Synthesis of CNTs via ethanol decomposition over ball-milled Fe2O3 coated copper sheets. Inorg Mater 43, 143–147 (2007). https://doi.org/10.1134/S0020168507020094
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/S0020168507020094