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Zirconia-based nanocrystals in the ZrO2-In2O3 system

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Abstract

Zirconia-based ZrO2-In2O3 nanocrystals are prepared by hydrothermal treatment of coprecipitated zirconium oxyhydroxide and indium hydroxide. Indium oxide is shown to dissolve predominantly in cubic zirconia nanocrystals. Its solubility in nanocrystalline zirconia notably exceeds the equilibrium In2O3 solubility in ZrO2 single crystals.

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References

  1. Shevchenko, V.Ya. and Barinov, S.M., Tekhnicheskaya keramika (Technical Ceramics), Moscow: Nauka, 1993.

    Google Scholar 

  2. Chen, K.L., Chang, S.T., and Tsao, H.K., Preparation of Zirconia Nanocrystals from Concentrated Zirconium Aqueous Solutions, J. Nanopart. Res., 2001, vol. 3, pp. 119–126.

    Article  CAS  Google Scholar 

  3. Oleinikov, N.N., Pentin, I.V., Murav’eva, G.P., et al., Finely Dispersed Metastable ZrO2-Based Phases, Zh. Neorg. Khim., 2001, vol. 46, no. 9, pp. 1413–1420.

    CAS  Google Scholar 

  4. Almjasheva, O.V. and Gusarov, V.V., Preparation of Nanocrystalline ZrO2-Y2O3 Powders and Related Ceramic Materials, XV Simpozium “Sovremennaya khimicheskaya fizika” (XV Symp. Modern Chemical Physics), 2003, p. 128.

  5. Pozhidaeva, O.V., Korytkova, E.N., Romanov, D.P., and Gusarov, V.V., Growth of Zirconia Nanocrystals in Different Hydrothermal Environments, Zh. Obshch. Khim., 2002, vol. 72, no. 6, pp. 910–914.

    Google Scholar 

  6. Tikhonov, P.A., Phases of Variable Composition with Controlled Electrical Properties Based on Refractory Oxides, Extended Abstract of Doctoral (Chem.) Dissertation, St. Petersburg, 1999.

  7. Artamonova, O.V., Almjasheva, O.V., Mittova, I.Ya., et al., Hydrothermal Synthesis of Zirconia-Based Nanocrystals in the ZrO2-In2O3 System, Zh. Neorg. Khim., 2004, vol. 49, no. 11, pp. 1789–1792.

    CAS  Google Scholar 

  8. Kharlamov, A.N., Turakulova, A.O., Lunma, I.V., and Lumn, V.V., Thermal Transformations of Zirconia Doped with Yitrium. Lanthanum, and Scandium Oxides, Zh. Fiz. Khim., 1997, vol. 71, no. 6, pp. 985–990.

    Google Scholar 

  9. Torayda, H., Yoshimura, M., and Somiya, S., Calibration Curve for Quantitative Analysis of Monoclinie-Tetragonal ZrO2 by X-ray Diffraction, J. Am. Ceram. Soc., 1984, vol. 67, no. 6, pp. C119–C121

    Google Scholar 

  10. Toropov, N.A., Barzakovskii, V.P., Lapin, V.V., and Kurtseva, N.N., Diagramuny sostovaniva silikatnvkh sistem: Spravochnik (Phase Diagrams of Silicate Systems: A Handbook), Moscow: Nauka, 1965.

    Google Scholar 

  11. Powder Diffraction File, Newtown Square: ICDD, 2001.

  12. Gusarov, V.V., Statics and Dynamics of Polycrystalline Systems Based on Refractory Oxides, Extended Abstract of Doctoral (Chem.) Dissertation, St. Petersburg, 1996

  13. Kingery, W.D., The Chemistry of Ceramre Grain Boundaries, Pure Appl. Chem., 1984, vol. 56, no. 12, pp. 1703–1714.

    CAS  Google Scholar 

  14. Palosz, B., Grzanka, E., Gierlotka, S., et al., Are Nanocrystalline Powders Two-Phase Materials: Prediction and Experimental Evidence, 20th Eur. Crystallographic Meeting, Kraków, 2001, p. 186.

  15. Ali-zade, R.A., Surface Layer of Magnetite Nanoparticles, XI Natsional’naya konferentsiya po rostu kristallov (XI Natl. Conf. on Crystal Growth), Moscow, 2004.

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Authors and Affiliations

  1. Voronezh State University of Architecture and Civil Engineering, ul. 20-letiva Oktvabrya 84, Voronezh, 394006, Russia

    O. V. Artamonova

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, St. Petersburg, 199155, Russia

    O. V. Almjasheva & V. V. Gusarov

  3. Voronezh State University, Universitetskaya pl. 1, Voronezh, 394006, Russia

    I. Ya. Mittova

Authors
  1. O. V. Artamonova
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  2. O. V. Almjasheva
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  3. I. Ya. Mittova
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  4. V. V. Gusarov
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Original Russian Text © O.V. Artamonova, O.V. Almjasheva, I.Ya. Mittova, V.V. Gusarov, 2006, published in Neorganicheskie Materialy, 2006, Vol. 42, No. 10, pp. 1178–1181.

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Artamonova, O.V., Almjasheva, O.V., Mittova, I.Y. et al. Zirconia-based nanocrystals in the ZrO2-In2O3 system. Inorg Mater 42, 1072–1075 (2006). https://doi.org/10.1134/S0020168506100049

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  • DOI: https://doi.org/10.1134/S0020168506100049

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