Abstract
We have studied the effects of the morphology and concentration of pore formers on the microstructure and gas permeability of porous zirconia-and lanthanum-gallate-based oxygen-ion-conducting ceramics. The results have been used to optimize the preparation conditions and composition of the ceramics. The resultant dense, fine-grained materials have porosities of up to }~56%.
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Kim, J. and Lin, Y.S., Synthesis and Characterization of Suspension-Derived, Porous Ion-Conducting Ceramic Membranes, J. Am. Ceram. Soc., 1999, vol. 82, no. 10, pp. 2641–2646.
Boaro, M., Vohs, J.M., and Gorte, R.J., Synthesis of Highly Porous Yttria-Stabilized Zirconia by Tape-Casting Methods, J. Am. Ceram. Soc., 2003, vol. 86, no. 3, pp. 395–400.
Ishihara, T., Matsuda, H., and Takita, Y., Doped LaGaO3 Perovskite Type Oxide as a New Oxide Ionic Conductor, J. Am. Ceram. Soc., 1994, vol. 116, no. 9, pp. 3801–3803.
Huang, P. and Petric, A., Superior Oxygen Ion Conductivity of Lanthanum Gallate Doped with Strontium and Magnesium, J. Electrochem. Soc., 1996, vol. 143, no. 5, pp. 1644–1648.
Huang, K., Tichy, R., and Goodenough, J., Superior Perovskite Oxide-Ion Conductor; Strontium-and Magnesium-Doped LaGaO3: Phase Relationships and Electrical Properties, J. Am. Ceram. Soc., 1998, vol. 81, no. 10, pp. 2565–2575.
Aleksandrovskii, V.V., Venskovskii, N.U., Kaleva, G.M., et al., Phase Composition, Microstructure, and Thermal Expansion of B2O3-Modified LaGaO3-Based Ceramics, Neorg. Mater., 2001, vol. 37, no. 6, pp. 758–763 [Inorg. Mater. (Engl. Transl.), vol. 37, no. 6, pp. 641–646].
Glavatskikh, T.Yu., Venskovskii, N.U., Aleksandrovskii, V.V., et al., Preparation and Properties of Oxygen-Selective LaGaO3-Based Ceramics with Mixed Ionic-Electronic Conduction, Neorg. Mater., 2003, vol. 39, no. 7, pp. 892–896 [Inorg. Mater. (Engl. Transl.), vol. 39, no. 7, pp. 759–763].
Politova, E.D., Stefanovich, S.Yu., Avetisov, A.K., et al., Processing, Structure, Microstructure, and Transport Properties of the Oxygen Conducting Ceramics (La,Sr)(Ga,M)Oy (M = Mg, Fe, Ni), J. Solid State Electrochem., 2004, vol. 8, no. 9, pp. 655–660.
Politova, E.D., Stefanovich, S.Yu., Aleksandrovskii, V.V., et al., The Lanthanum Gallate Based Mixed Conducting Perovskite Ceramics, Phys. Status Solidi, 2005, vol. 2, no. 1, pp. 196–199.
Dimitriu, E., Bunescu, C.M., Iuga, A., and Ramer, R., Influence of Microstructure on Physical Properties of PT Porous Ceramics, Ferroelectrics, 2002, vol. 270, pp. 45–50.
Galassi, C., Roncari, E., Capiani, C., et al., Processing of Porous PZT Materials for Under Water Acoustics, Ferroelectrics, 2002, vol. 268, pp. 47–52.
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Original Russian Text © G.M. Kaleva, N.V. Golubko, S.V. Suvorkin, G.V. Kosarev, I.P. Sukhareva, A.K. Avetisov, E.D. Politova, 2006, published in Neorganicheskie Materialy, 2006, Vol. 42, No. 7, pp. 881–887.
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Kaleva, G.M., Golubko, N.V., Suvorkin, S.V. et al. Preparation and microstructure of ZrO2-and LaGaO3-based high-porosity ceramics. Inorg Mater 42, 799–805 (2006). https://doi.org/10.1134/S0020168506070193
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DOI: https://doi.org/10.1134/S0020168506070193