Abstract
The effect of γ-irradiation on the surface properties of polypropylene (PP) has been studied as a function of the absorbed dose. It has been established that γ-irradiation leads to an increase in the free surface energy of the polymer, its acid–base component, and the surface polarity. An analysis of the IR spectra of γ-irradiated PP samples indicated the formation of oxygen-containing groups in the composition of PP macromolecules, which was confirmed by the values of the surface acidity parameter. An increase in the dose led to an increase in the concentration of products of radiation-induced conversion. A significant increase in the melt flow index (MFI) of polypropylene up to an absorbed dose of 150 kGy also evidenced the occurrence of oxidation and destruction processes. The MFI decreased at radiation doses above 150 kGy, and this fact indicates that such doses of ionizing radiation lead to the predominance of the processes of polymer structuring or crosslinking.
Similar content being viewed by others
REFERENCES
Gavrila, D.E., Stoian, V., Caramitu, A., and Mitrea, S., Composite Materials, Chowdhury, M.A., Armenta, J.L.R., Rahman, M.M., Asiri, A., and Inamuddin, I., Eds., London: IntechOpen, 2020, p. 774. www.intechopen.com/chapters/71600. Accessed December 27, 2022.
Van Lierde, S., Med. Device Technol., 2004, vol. 15, no. 5, p. 33.
Lisanevich, M.S., Galimzyanova, R.Yu., Khakimullin, Yu.N., Fedorova, T.A., Mezentseva, E.V., and Ivanov, V.V., Izv. Vyssh. Uchebn. Zaved., Tekhnol. Tekstil. Prom-sti, 2021, no. 5, p. 94.
Lisanevich, M.S., Galimzyanova, R.Yu., Musin, I.N., and Makarov, T.V., Sterilizatsiya meditsinskikh izdelii. Uchebnoe posobie (Sterilization of Medical Devices: Textbook), Kazan: Shkola, 2020.
Galimzyanova, R.Yu., Rakhmatullina, E.R., Lisanevich, M.S., and Khakimullin, Yu.N., Vestn. Tekhnol. Univ., 2020, vol. 23, no. 2, p. 19.
Lisanevich, M.S., Rakhmatullina, E.R., Khakimullin, Yu.N., Galimzyanova, R.Yu., Akhmadullin, R.M., and Perukhin, Y.V., Key Eng. Mater. Trans., 2019, vol. 816, p. 328.
Ivanov, V.S., Radiation Chemistry of Polymers, London: CRC,1992.
Shaimukhametova, I.F., Shigabieva, Y.A., Bogdanova, S.A., and Allayarov, S.R., High Energy Chem., 2020, vol. 54, no. 2, p. 111.
Shaimukhametova, I.F., Allayarov, S.R., Demidov, S.V., and Bogdanova, S.A., High Energy Chem., 2021, vol. 55, no. 5, p. 381.
Allayarov, S.R., Confer, M.P., Bogdanova, S.A., Shigabieva, Y.A., and Dixon, D.A., Polym. Degrad. Stab., 2021, vol. 191, p. 109697.
Allayarov, S.R., Confer, M.P., Demidov, S.V., Malkov, G.V., Bogdanova, S.A., Shaimukhametova, I.F., Nikolsky, V.G., Perukhin, Yu.V., Podvalnaya, Yu.V., Zyukin, I.V., and Dixon, D.A., Polymer, 2021, vol. 237, p. 124342.
Allayarov, S.R., Confer, M.P., Bogdanova, S.A., Rudneva, T.N., Allayarova, U.Yu., Shaimukhametova, I.F., Demidov, S.V., Mishchenko, D.V., Klimanova, E.N., Sashenkova, T.E., Chekalina, S.D., Aldoshin, S.M., and Dixon, D.A., Radiat. Phys. Chem., 2022, vol. 201, p. 110436.
Berger, E.J., J. Adhes. Sci. Technol., 1990, vol. 4, no. 5, p. 373.
Starostina, I.A., Stoyanov, O.V., and Kraus, E., Razvitie metodov smachivaniya dlya otsenki sostoyaniya poverkhnosti (Development of Wetting Methods for Surface Statwe Assessment), Kazan: KNITU, 2019.
Starostina, I.A. and Stoyanov, O.V., Kislotno-osnovnye vzaimodeistviya i adgeziya v metall-polimernykh sistemakh (Acid–Base Interactions and Adhesion in Metal–Polymer Systems), Kazan: KGTU, 2010.
Fowkes, F.M. and Wendt, R.C., J. Phys. Chem., 1963, vol. 67, no. 12, p. 2538.
Owens, D.K., J. Appl. Polym. Sci., 1969, vol. 13, p. 1741.
Vijayendran, B.R., J. Appl. Polym. Sci., 1979, vol. 23, no. 3, p. 733.
Funding
This work was supported by a state contract no. АААА-А19-119041090087-4.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by V. Makhlyarchuk
Rights and permissions
About this article
Cite this article
Bogdanova, S.A., Shaimukhametova, I.F., Galimzyanova, R.Y. et al. Surface Properties of Gamma-Irradiated Polypropylene. High Energy Chem 57, 351–355 (2023). https://doi.org/10.1134/S0018143923040057
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018143923040057