Abstract
It has been shown that the quantum yield of the dye-photosensitized decomposition of 2-mercaptobenzothiazole (MBT) in aqueous solutions increases in the case of irradiation of dyes in the presence of electron acceptors. In the presence of electron donors, the quantum yields of the photosensitized decomposition reaction of MBT either remains unchanged or decreases. The donor thiocyanate and iodide ions were the exception; in this case, this was due to the formation of radical anions in the subsequent reactions of iodine and thiocyanate radicals with their anions, respectively. A mechanism has been suggested for the photosensitization of 2-mercaptobenzothiazole decomposition by dyes in the presence of electron acceptors and donors.
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REFERENCES
Malouki, M.A., Giry, G., Besse, P., Combourieu, B., Sancelme, M., Bonnemoy, F., Richard, C., and Delort, A.-M., Environ. Toxicol. Chem., 2003, vol. 22, no. 9, p. 2013.
De Wever, H., Besse, P., and Verachtert, H., Appl. Microbiol. Biotechnol., 2001, vol. 57, no. 5, p. 620.
Suzuki, S., Emilie, P., Urano, T., Takahara, S., and Yamaoka, T., Polymer, 2005, vol. 46, no. 7, p. 2238.
Stephensen, E., Adolfsson-Erici, M., Hulander, M., Parkkonen, J., and Forlin, L., Aquat. Toxicol., 2005, vol. 75, no. 2, p. 136.
Yang, H., Sun, Y., Ji, J., Song, W., Zhu, X., Yao, Y., and Zhang, Z., Corros. Sci., 2008, vol. 50, no. 11, p. 3160.
Antonopoulou, M., Evgenidou, E., Lambropoulou, D., and Konstantinou, I., Water Res., 2014, vol. 53, p. 215.
Fries, E., Gocht, T., and Klasmeier, J., J. Environ. Monit., 2011, vol. 13, no. 10, p. 2838.
Sorahan, T., Occup. Environ. Med., 2009, vol. 66, no. 4, p. 269.
Ivanov, V.L. and Lyashkevich, S.Yu., High Energy Chem., 2018, vol. 52, no. 6, p. 451.
Ivanov, V.L. and Artyukhin, A.B., High Energy Chem., 1998, vol. 32, no. 5, p. 333.
Eksperimental'nye metody khimii vysokikh energii (Experimental Methods in High Energy Chemistry), Mel’nikov, M.Ya, Ed., Moscow: Izd. MGU 2009.
Korobov, V.E. and Chibisov, A.K., Usp. Khim., 1983, vol. 52, no. 1, p. 43.
Görner, H., Photochem. Photobiol. Sci., 2008, vol. 7, p. 371.
Kraljic, I. and Lindqvist, L., Photochem. Photobiol., 1974, vol. 20, p. 351.
Neckers, D.C. and Valdes-Aguilera, O.M., Adv. Photochem., 1933, vol. 18, p. 315.
Milosavljevic, B.H. and LaVerne, J.A., J. Phys. Chem. A, 2005, vol. 109, p. 165.
Yu, X.-Y. and Barker, J.R., J. Phys. Chem. A, 2003, vol. 107, p. 1325.
Schwarz, H.A. and Bielski, B.H.J., J. Phys. Chem., 1986, vol. 90, p. 1445.
Behar, D., Bevan, P.L.T., and Scholes, G., J. Phys. Chem., 1972, vol. 76, no. 11, p. 1537.
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Translated by V. Makhlyarchuk
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Ivanov, V.L., Lyashkevich, S.Y. Influence of Electron Acceptors and Donors on the Dye-Photosensitized Decomposition of 2-Mercaptobenzothiazole. High Energy Chem 54, 259–262 (2020). https://doi.org/10.1134/S0018143920040074
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DOI: https://doi.org/10.1134/S0018143920040074