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Spectral and kinetic parameters of transient species in the photolysis of naphthylmethylideneiminospironaphthopyran by excitation at different wavelengths: Nano- and femtosecond laser photolysis

  • Photochemistry
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Abstract

Intramolecular processes occurring in a photobifunctional compound (PBC) comprising the spironaphthopyran and hydroxyazomethine moieties have been studied in methanol solutions by femtosecond laser photolysis using light with wavelengths of 340 and 490 nm. At the excitation wavelength of 490 nm, the cis-trans photoisomerization in the azomethine moiety occurs in the S1 state. In the case of PBC photolysis with 340-nm light, the opening of the spiro bond of the spiropyran moiety (formation of the X form) also takes place during relaxation of the Sn state to the S1 state followed by isomerization to the merocyanine form. The spectral and kinetic characteristics of different electronically excited have been were determined. The data have been compared with those of nanosecond laser photolysis.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    V. A. Nadtochenko

  2. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119334, Russia

    P. P. Levin

  3. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    N. L. Zaichenko, F. E. Gostev, I. V. Shelaev, A. I. Shienok, L. S. Kol’tsova, O. M. Sarkisov & A. A. Berlin

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  1. V. A. Nadtochenko
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  2. P. P. Levin
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  3. N. L. Zaichenko
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  4. F. E. Gostev
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  5. I. V. Shelaev
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  6. A. I. Shienok
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  7. L. S. Kol’tsova
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  8. O. M. Sarkisov
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  9. A. A. Berlin
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Correspondence to V. A. Nadtochenko.

Additional information

Original Russian Text © V.A. Nadtochenko, P. P. Levin, N.L. Zaichenko, F.E. Gostev, I.V. Shelaev, A.I. Shienok, L.S. Kol’tsova, O.M. Sarkisov, A.A. Berlin, 2013, published in Khimiya Vysokikh Energii, 2013, Vol. 47, No. 2, pp. 121–128.

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Nadtochenko, V.A., Levin, P.P., Zaichenko, N.L. et al. Spectral and kinetic parameters of transient species in the photolysis of naphthylmethylideneiminospironaphthopyran by excitation at different wavelengths: Nano- and femtosecond laser photolysis. High Energy Chem 47, 120–126 (2013). https://doi.org/10.1134/S0018143913030132

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  • DOI: https://doi.org/10.1134/S0018143913030132

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