Abstract
The transformation of a benzene-argon mixture in dielectric-barrier discharge (DBD) was studied. Benzene-soluble polymeric compounds (76.5 wt %), biphenyl (7.6 wt %), and phenylcyclohexadienes (9 wt %) are the major products. Monoalkylbenzenes, cyclohexadienes, and ethynylbenzene are in trace amounts in the reaction mixture. The benzene conversion per pass through the discharge zone was 5.5 wt %. The possible mechanism of the benzene transformation in DBD was suggested on the basis of experimental data and theoretical calculations.
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Original Russian Text © S.A. Perevezentsev, S.V. Kudryashov, S.E. Boganov, A.Yu. Ryabov, G. S. Shchegoleva, 2011, published in Khimiya Vysokikh Energii, 2011, Vol. 45, No. 1, pp. 65–68.
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Perevezentsev, S.A., Kudryashov, S.V., Boganov, S.E. et al. Transformations of benzene-argon mixture in barrier discharge. High Energy Chem 45, 62–65 (2011). https://doi.org/10.1134/S0018143911010127
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DOI: https://doi.org/10.1134/S0018143911010127