Abstract
The feasibility of direct oxidation of benzene to phenol by oxygen or air in dielectric-barrier discharge (DBD) under conditions of effective removal of the products from the discharge operation zone is shown. It has been established that the control of the reactor temperature in the process of benzene oxidation in DBD plasma is a good practice for controlling both the benzene conversion and the product composition. A possible mechanism of the process is proposed.
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Funding
The work was carried out within the framework of the state task of the Institute of Petroleum Chemistry of the Siberian Branch of the Russian Academy of Sciences, funded by the Ministry of Science and Higher Education of the Russian Federation, project no. FWRN-2021-0003.
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Translated by S. Zatonsky
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Ochered’ko, A.N., Kudryashov, S.V., Ryabov, A.Y. et al. Direct Oxidation of Benzene to Phenol in a Dielectric-Barrier Discharge Reactor. High Energy Chem 56, 284–288 (2022). https://doi.org/10.1134/S0018143922040129
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DOI: https://doi.org/10.1134/S0018143922040129