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Effect of heat and solvent treatment on radiation grafting of acrylic acid to poly(ethylene terpehthalate)

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Abstract

Direct radiation graft polymerization of acrylic acid onto oriented poly(ethylene terephthalate) films and fibers subjected to thermal treatment and treated with structure-active solvents, such as dichloroethane and dioxane, was studied. Based on the results of thermomechanical analysis, X-ray diffraction, sorption, and acrylic acid grafting, conclusions were drawn concerning the character of structural changes in poly(ethylene terephthalate) exposed to structure-active solvents. The physicochemical properties of the graft copolymers obtained were examined, including the resistance against γ-radiation.

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Authors and Affiliations

  1. Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, ul. Surganova 13, Minsk, 220072, Belarus

    V. I. Martinovich & A. P. Polikarpov

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  1. V. I. Martinovich
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  2. A. P. Polikarpov
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Original Russian Text © V.I. Martinovich, A.P. Polikarpov, 2006, published in Khimiya Vysokikh Energii, 2006, Vol. 40, No. 3, pp. 185–190.

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Martinovich, V.I., Polikarpov, A.P. Effect of heat and solvent treatment on radiation grafting of acrylic acid to poly(ethylene terpehthalate). High Energy Chem 40, 149–153 (2006). https://doi.org/10.1134/S0018143906030040

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  • DOI: https://doi.org/10.1134/S0018143906030040

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