Skip to main content
Log in

Composition and Distribution of Saturated Hydrocarbons in the Thermal Waters and Vapor–Water Mixture of the Mutnovskii Geothermal Field and Uzon Caldera, Kamchatka

  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract

The paper presents data on the composition and molecular-mass distribution of saturated hydrocarbons in sterile vapor–water mixture from wells and in high-temperature springs in the Mutnovskii hydrothermal area and Uzon caldera. The condensate of the vapor–water mixture and thermal waters from the Mutnovskii area contain low-molecule n-alkanes, which were generated by thermogenic processes. The boiling mud pot of the Donnoe fumarole field typically contains hydrocarbons whose origin is likely related to thermocatalytic transformations of the biomass of thermophilic microorganisms. A separate type of the molecular-mass distribution is typical of the geyser in the caldera of Uzon volcano: this material contains n‑alkanes, which were generated by two processes: chemical re-synthesis of floral organic remnants and biogenic synthesis with the probable involvement of bacteria and algae.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. A. Aubrey, H. Cleaves, and J. Bada, “The role of submarine hydrothermal systems in the synthesis of amino acids,” Origins Life Evol. Biosphere 39, 91–108 (2009).

    Article  Google Scholar 

  2. V. L. Barsukov and B. N. Ryzhenko, “Temperature evolution of pore solutions in equilibrium with rocks of various silica contents,” Geol. Ore Deposits, 43 (3), 184–202 (2001).

    Google Scholar 

  3. O. K. Bazhenova, O. A. Arefiev, and E. B.Frolov, “Oil of the volcano Uzon caldera, Kamchatka,” Org. Geochem. 29(1–3), 421–428 (1998).

    Article  Google Scholar 

  4. N. S. Beskrovnyi and B. A. Lebedev, “Oil occurrence in the Uzon Volcano caldera,” Dokl. Akad. Nauk SSSR 201(4), 953–956 (1971).

    Google Scholar 

  5. E. E. Bray and E. D. Evans, “Distribution of n-paraffines as a clue to recognition of source beds,” Geochim. Cosmochim. Acta 22 (1), 2–15 (1961).

    Article  Google Scholar 

  6. O. V. Chudaev, V. A. Chudaeva, G. A. Karpov, U. M. Edmunds, and P. Shand, Geochemistry of waters of main geothermal areas of Kamchatka (Dal’nauka Vladivostok, 2000) [in Russian].

    Google Scholar 

  7. H. J. Cleaves, A. D. Aubrey, and J. L. Bada, “An evaluation of critical parameters for abiotic peptide synthesis in submarine hydrothermal systems,” Origins Life Evol. Biosphere 39, 109–126 (2009).

    Article  Google Scholar 

  8. M. V. Efimova, Extended Abstract of Candidate’s Dissertation in Geology and Mineralogy (TIBOKH DVO RAN, Vladivostok, 2005) [in Russian].

  9. J. Fiebig, A. B. Woodland, J. Spangenberg, and W. Oschmann, “Natural evidence for rapid abiogenic hydrothermal generation of CH4,” Geochim. Cosmochim. Acta 71, 3028–3039 (2007).

    Article  Google Scholar 

  10. Q. Fu, L. B. Sherwood, J. Horita, G. Lacrampe-Couloume, and J. W. E. Seyfried, “Abiotic formation of hydrocarbons under hydrothermal conditions: constraints from chemical and isotope data,” Geochim. Cosmochim. Acta 71, 1982–1998 (2007).

    Article  Google Scholar 

  11. E. M. Galimov, V. S. Sevast’yanov, A. I. Kamaleeva, O. V. Kuznetsova, I. V. Konopleva, L. N. Vlasova, and G. A. Karpov, “Hydrocarbons from a volcanic area. Oil seeps in the Uzon caldera, Kamchatka,” Geochem. Int. 53 (12), 1019–1027 (2015).

    Article  Google Scholar 

  12. L. A. Garetova, “Hydrocarbons in the lagoonal estuaries of the Tatar Strait,” Izv. TINRO 172, 196–207 (2013).

    Google Scholar 

  13. L. S. Glebov and G. A. Kliger, “Molecular-weight distribution of Fischer Tropsch synthesis products,” Usp. Khimii 63 (2), 192–202 (1994).

    Google Scholar 

  14. N. G. Holm and E. Andersson, “Hydrothermal simulation experiments as a tool for studies for the origin of life on Earth and other terrestrial planets: a review,” Astrobiology 5 (4), 444–460 (2005).

    Article  Google Scholar 

  15. N. G. Holm and J. L. Charlou, “Initial indications of abiotic formation of hydrocarbons in the Rainbow ultramafic hydrothermal system, Mid-Atlantic Ridge,” Earth. Planet. Sci. Lett. 191, 1–8 (2001).

    Article  Google Scholar 

  16. J. M. Hunt, Petroleum Geochemistry and Geology (W.H. Freeman and Company, San Francisco, 1979).

    Google Scholar 

  17. V. A. Isodorov, I. G. Zenkevich, and G. A. Karpov, “Volatile organic compounds in the vapor-gas vents of some volcanoes and hydrothermal systems of Kamchatka,” Vulkanol. Seismol., no. 3, 19–25 (1991).

  18. G. A. Karpov, Modern Hydrothermal Vents and Mercury–Stibium–Arsenic Mineralization (Moscow, Nauka, 1988) [in Russian].

    Google Scholar 

  19. V. N. Kompanichenko and V. A. Poturay, “Variations of organic matter in waters of the Kkul’dur geothermal deposit,” Tikhookean. Geol. 34 (4), 96–107 (2015).

    Google Scholar 

  20. V. N. Kompanichenko, V. A. Poturay, and K. V. Shlufman, “Hydrothermal systems of Kamchatka as the model for prebiotic environment,” Origins Life Evol. Biosphere 45 (1–2), 93–103 (2015).

    Article  Google Scholar 

  21. V. N. Kompanichenko, V. A. Poturay and G. A. Karpov, “Organic compounds in thermal water: the Mutnovskii Area and the Uzon Caldera,” J. Volcanol. Seismol. 10 (5), 305–319 (2016).

    Article  Google Scholar 

  22. C. Konn, J. L. Charlou, N. G. Holm, and O. Mousis, “The production of methane, hydrogen, and organic compounds in ultramafic-hosted hydrothermal vents of the Mid-Atlantic Ridge,” Astrobiology 15 (5), 381–399 (2015).

    Article  Google Scholar 

  23. A. E. Kontorovich, S. B. Bortnikova, G. A. Karpov, V. A. Kashirtsev, E. A. Kostyreva, and A. N. Fomin, “Uzon volcano caldera (Kamchatka): a unique natural laboratory of the present-day napthide genesis,” Russ. Geol. Geophys. 52 (8), 768–772 (2011).

    Article  Google Scholar 

  24. N. P. Laverov, B. N. Ryzhenko, and V. L. Barsukov, “Redox potential of hydrothermal systems in granitic rocks,” Dokl. Earth Sci. 349 (3), 873–877 (1996).

    Google Scholar 

  25. T. M. McCollom, “Laboratory simulations of abiotic hydrocarbon formation in Earth’s deep subsurface,” Rev. Mineral. Geochem. 75, 467–494 (2013).

    Article  Google Scholar 

  26. L. M. Mukhin, V. B. Bondarev, E. A. Vakin, I. I. Il’yukhina, V. I. Kalinichenko, E. I. Milekhina, and E. N. Safonova, “Aminoacids in the hydrothermal vents of South Kamchatka,” Dokl. SSSR 244 (4), 974–977 (1979).

    Google Scholar 

  27. I. A. Nemirovskaya, “Concentration and composition of hydrocarbons in bottom sediments from the Sakhalin shelf,” Geochem. Int. 46(4), 378–385 (2008).

    Article  Google Scholar 

  28. A. R. Poshibaeva, Extended Abstract of Candidate’s Dissertation in Geology and Mineralogy (RGU Nefti gaza, Moscow, 2015).

  29. V. A. Poturay, “Organic matter in ground- and surface waters in the area of the Annenskii geothermal field, Russian Far East,” Geochem. Int. 55 (4), 393–400(2017a).

    Article  Google Scholar 

  30. V. A. Poturay, “Composition and distribution of n-alkanes in the nitrogen thermal vents of the Russian Far East,” Tikhookean. Geol. 36 (4), 109–119 (2017b).

    Google Scholar 

  31. A. I. Rushdi, and B. R. T. Simoneit, “Lipid formation by aqueous Fischer-Tropsch-type synthesis over a temperature range of 100 to 400°C,” Origins Life Evol. Biosphere 31, 103–118 (2001).

    Article  Google Scholar 

  32. B. N. Ryzhenko, V. L. Barsukov, and S. N. Knyazeva, “Chemical characteristics (composition, pH, and Eh) of a rock–water system: 1. The granitoids–water system,” Geochem. Int. 34(5), 390-407 (1996).

    Google Scholar 

  33. B. N. Ryzhenko, E. S. Sidkina, and E. V. Cherkasova, “Thermodynamic modeling of water-rock systems to evaluate their generative potential for hydrocarbons,” Geochem. Int. 53 (9), 825–837 (2015).

    Article  Google Scholar 

  34. E. Shock and P. Canovas, “The potential for abiotic organic synthesis and biosynthesis at seafloor hydrothermal systems,” Geofluids 10, 161–192 (2010).

    Google Scholar 

  35. N. A. Shulga, V. I. Peresypkin, and I. A. Revelskii, “Composition research of n-alkanes in the samples of hydrothermal deposits of the Mid-Atlantic Ridge by means of gas chromatography–mass spectrometry,” Oceanology 50 (4), 479–487 (2010).

    Article  Google Scholar 

  36. B. R. T. Simoneit, “Maturation of organic matter and oil formation: hydrothermal aspect,” Geokhimiya, No. 2, 236–254 (1986).

    Google Scholar 

  37. B. R. T. Simoneit, “Prebiotic organic synthesis under hydrothermal conditions: an overview,” Adv. Space Res. 33 (1), 88–94 (2004).

    Article  Google Scholar 

  38. B. R. T. Simoneit, D. W. Deamer, and V. N. Kompanichenko, “Characterization of hydrothermally generated oil from the Uzon caldera, Kamchatka,” Appl. Geochem. 24, 303–309 (2009).

    Article  Google Scholar 

  39. S. D. Varfolomeev, G. A. Karpov, G.-A. Sinal, S. M. Lomakin, and E. N. Nikolaev, “The youngest oil on Earth,” Dokl. Akad. Nauk 438 (3), 345–347 (2011).

    Google Scholar 

  40. G. A. Zavarzina, G. A. Karpov, V. M. Gorlenko, R. S. Golovacheva, L. M. Gerasimenko, E. A. Bonch Osmolovskaya, and V. K. Orleanskii, Caldera Microorganisms (Nauka, Moscow, 1989) [in Russian].

    Google Scholar 

  41. M. E. Zelensky, Y. A. Taran, E. O. Dubinina, V. N. Shapar’, and E. A. Polyntseva, “Sources of volatiles for a subduction zone volcano: Mutnovsky volcano, Kamchatka,” Geochem. Int. 50 (6), 502–521 (2012).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to V. A. Poturay or V. N. Kompanichenko.

Additional information

Translated by E. Kurdyukov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Poturay, V.A., Kompanichenko, V.N. Composition and Distribution of Saturated Hydrocarbons in the Thermal Waters and Vapor–Water Mixture of the Mutnovskii Geothermal Field and Uzon Caldera, Kamchatka. Geochem. Int. 57, 74–82 (2019). https://doi.org/10.1134/S0016702919010087

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702919010087

Keywords:

Navigation