Skip to main content
Log in

Fluid phases in carbonado and their genetic significance

  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract

Using the method of pyrolysis—gas chromatography, the composition of fluid inclusions in Brazilian carbonado and associating monocrystalline diamonds were investigated for the first time. Temperature trends were obtained for the composition of the released gas phase; based on this data, it was concluded that the diamonds include two generations of inclusions: those decrepitating at temperatures below 500°C and above 500°C. It was found that the fluid released from carbonado at high temperatures is anomalously enriched in carbon monoxide, which is strongly different from the characteristics of both the products of intracrustal mineral, rock, and ore formation and the results of crust—mantle interaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. I. Chepurov, A. A. Tomilenko, A. P. Shebanin, and N. V. Sobolev, “Fluid Inclusions in Natural Diamonds from Yakutian Placers,” Dokl. Akad. Nauk 336, 662–665 (1994).

    Google Scholar 

  2. A. A. Tomilenko, A. I. Chepurov, Yu. N. Pal’yanov, et al., “Volatile Components in the Upper Mantle: Fluid Inclusion Data,” Geol. Geofiz. 38, 276–285 (1997).

    Google Scholar 

  3. C. E. Melton and A. A. Giardini, “The Composition and Significance of Gas Released from Natural Diamonds from Africa and Brazil,” Am. Mineral. 59, 775–782 (1974).

    Google Scholar 

  4. C. E. Melton and A. A. Giardini, “Experimental Evidence That Oxygen is Principal Impurity in Natural Diamonds,” Nature 263, 309–310 (1976).

    Article  Google Scholar 

  5. C. E. Melton and A. A. Giardini, “The Nature and Significance of Occluded Fluids in Three Indian Diamonds,” Am. Mineral. 66, 746–750 (1981).

    Google Scholar 

  6. A. A. Giardini and C. E. Melton, “The Nature of Cloudlike Inclusions in Two Arkansas Diamonds,” Am. Mineral. 60, 931–933 (1975).

    Google Scholar 

  7. O. Navon, I. D. Hutcheon, G. R. Rossman, and G. R. Wasserburg, “Mantle-Derived Fluids in Diamond Micro-Inclusions,” Nature 355, 784–789 (1988).

    Article  Google Scholar 

  8. M. Schrauder and O. Navon, “Hydrous and Carbonatic Mantle Fluids in Fibrous Diamonds from Jwaneng, Botswana,” Geochim. Cosmochim. Acta 58, 761–771 (1994).

    Article  Google Scholar 

  9. E. S. Izraeli, J. W. Harris, and O. Navon, “Brine Inclusions in Diamonds: A New Upper Mantle Fluid,” Mar. Geol. 187, 323–332 (2001).

    Google Scholar 

  10. N. Takaoka and M. Ozima, “Rage Gas Elemental Abundances and Isotopic Compositions in Diamonds,” Geol. Surv. Open-File Rept., No. 701a, 418–420 (1978).

  11. N. Takaoka and M. Ozima, “Rage Gas Isotopic Compositions in Diamonds,” Nature 271, 45–46 (1978).

    Article  Google Scholar 

  12. Z. V. Bartoshinskii, S. N. Bekesha, T. G. Vinnichenko, et al., “Gas Admixtures in Yakutian Diamonds,” Mineral. Sb., No. 1, 25–32 (1987).

  13. I. V. Popivyak, B. G. Demin, V. V. Levitskii, and V. I. Koptil’, “New Data on the Volatiles of Mantle Mineral-Forming Media,” Dokl. Akad. Nauk SSSR 254, 1238–1241 (1980).

    Google Scholar 

  14. Z. V. Bartoshinskii, S. N. Bekesha, T. G. Vinnichenko, et al., “Volatiles in Diamonds from the Northern Part of the Russian Platform,” Mineral. Sb., No. 2, 14–18 (1990).

  15. V. I. Silaev, V. A. Petrovsky, A. E. Sukharev, and M. Martins, “New Contribution in the Mineralogy of Carbonado: Summary of Study Results,” in Proceedings of Conference Diamond Geology—Present and Future (50th Anniversary of Mirny and Diamond Mining Industry in Russia) (Voronezh, 2005), pp. 695–705 [in Russian].

  16. V. A. Petrovsky, M. Martins, V. P. Lyutoev, et al., “Mineralogical and Genetic Features of Carbonado from Minas Gerais (Brazil),” in Syktyvkar Mineralogical Contributions, No. 33, Tr. Inst. Geol. Komi NTs UrO RAN, Issue 115, 41–69 (2003).

  17. V. A. Petrovsky, A. E. Sukharev, V. P. Filonenko, and E. N. Yakovlev, “Ballas and Carbonado-Type Diamond Polycrystalline Aggregates: Theory, Nature, and Experiment,” in Syktyvkar Mineralogical Contributions, No. 33, Tr. Inst. Geol. Komi NTs UrO RAN, Issue 115, 37–54 (2003).

  18. O. F. Mironova, V. B. Naumov, and A. N. Salazkin, “Nitrogen in Mineral-Forming Fluids. Gas-Chromatography Determination in Fluid Inclusions,” Geokhimiya, No. 2, 979–991 (1992).

  19. V. I. Silaev, V. A. Petrovsky, S. N. Shanina, and A. E. Sukharev, “Gas-Fluid Inclusions in Carbonado as Source of Genetic Information,” in Materials of 11th International Conference on Structure, Geodynamics, and Metallogenic Processes in Lithosphere (Geoprint, Syktyvkar, 2005), pp. 324–325 [in Russian].

  20. V. A. Petrovsky, V. I. Silaev, A. E. Sukharev, et al., “Gas-Fluid Inclusions in Carbonado,” in Proceedings of 12th International Conference on Thermobarogeochemistry, Aleksandrov, Russia, 2005 (VNIISIMS, Aleksandrov, 2005), pp. 32–56 [in Russian].

    Google Scholar 

  21. V. A. Petrovsky, V. I. Silaev, A. E. Sukharev, et al., “Gas-Fluid Inclusions in Carbonado and their Genetic Information,” in Proceedings of 12th International Scientific and Technical Conference on High Technology in Russian Industry, Moscow, Russia, 2006 (Moscow, 2006), pp. 434–446 [in Russian].

  22. M. V. Luk’yanovich and G. I. Veres, “Thermobarographic Study of Natural Diamonds,” Almazy, No. 3, 4–5 (1973).

  23. E. M. Galimov, F. V. Kaminskii, and L. A. Kodina, “New Data on the Carbon Isotope Composition of Carbonado,” Geokhimiya, No. 5, 723–726 (1985).

  24. E. A. Rogozina, Gas Formation during the Catagenesis of Organic Matter in Sedimentary Rocks (Nauka, Leningrad, 1983) [in Russian].

    Google Scholar 

  25. M. I. Kucher, V. A. Petrovsky, A. E. Sukharev, et al., “Carbon Isotopes in Brazilian Carbonado and Diamond Monocrystals,” in Proceedings of International Conference on New Data in Earth Sciences (Leon, XXI, Moscow, 2005), Vol. 2, p. 178 [in Russian].

    Google Scholar 

  26. A. N. Krot, T. V. Posukhova, and E. V. Guseva, “Genesis of Garnets with Hydrocarbon Inclusions from the Mir Kimberlite Pipe, Yakutia,” in Proceedings of All-Russia Mineralogical Conference on Mineraloids (Komi FAN SSSR, Syktyvkar, 1989), p. 39 [in Russian].

    Google Scholar 

  27. E. M. Galimov and V. I. Gerasimovskii, “Carbon Isotope Composition of the Magmatic Rocks of Iceland,” Geokhimiya, No. 11, 1615 (1973).

  28. P. Deines, “The Carbon Isotopic Composition of Diamond: Relationship to Diamond Shape, Color, Occurrence and Vapor Composition,” Geochim. Cosmochim. Acta 44, 943–961 (1980).

    Article  Google Scholar 

  29. F. A. Letnikov, “Fluid Regime of Endogenous Processes in the Continental Lithosphere and Metallogenic Problems,” in Problems of Global Geodynamics (Geos, Moscow, 2000), pp. 204–224 [in Russian].

    Google Scholar 

  30. Yu. D. Pushkarev, “Two Interaction Modes of Crustal and Mantle Materials and a New Approach to Problems of Deep Ore Formation,” Dokl. Akad. Nauk 355, 524–526 (1997) [Dokl. Earth Sci. 355A, 881–883 (1997)].

    Google Scholar 

  31. Yu. D. Pushkarev, B. M. Gorokhovskii, A. M. Larin, et al., “Role of Crustal and Mantle Material in the Formation of Giant Endogenous Deposits: Isotope-Geochemical Approach,” Regional Geol. Metallogen., No. 11, 73–80 (2000).

  32. A. A. Kadik and O. A. Lukanin, Upper Mantle Degassing During Melting (Nauka, Moscow, 1986) [in Russian].

    Google Scholar 

  33. N. I. Bryanchaninova, “Gas Inclusions in the Rock-Forming Silicates of the Ultrabasic Rocks of the Polar Urals as Characteristics of Mantle Fluid Regime,” in Diamond and Diamond Potential of the Timan-Uralian Region (Geoprint, Syktyvkar, 2001), pp. 88–90 [in Russian].

    Google Scholar 

  34. V. A. Simonov, G. L. Kashintsev, and A. E. Izokh, “Volatile Components in Deep-Seated Enclaves from Southern Tuva and Red Sea Region,” in Lithotectonic Complexes of Southeastern Tuva (Nauka, Novosibirsk, 1989), pp. 45–56 [in Russian].

    Google Scholar 

  35. A. V. Shcherbakov, S. F. Trufanova, and R. N. Murogova, “Conditions of Formation of Mineral Assemblages from the Chromite Deposits of the Polar Urals: Evidence from Gas Components in the Rocks,” in Proceedings of 10th International Conference on Thermobarogeochemistry, Aleksandrov, Russia, 2001 (VNIISIMS, Aleksandrov, 2001), pp. 61–78 [in Russian].

    Google Scholar 

  36. N. V. Sokerina and S. N. Shanina, “Gas-Liquid Inclusions in Gangue Quartz from the Sinil’ga Occurrence, Nether-Polar Urals,” Proceedings of 10th International Conference on Thermobarogeochemistry, Aleksandrov, Russia, 2001 (VNIISIMS, Aleksandrov, 2001), pp. 374–386 [in Russian].

    Google Scholar 

  37. V. A. Petrovsky, V. I. Silaev, A. E. Suharev, et al., “Micro-Nanoscale Inclusions in Carbonados and Their Genetic Significance,” in Proceedings of 4th International Mineralogical Seminar on the Theory, History, Philosophy, and Practice of Mineralogy, Syktyvkar, Russia, 2006 (Geoprint, Syktyvkar, 2006), pp. 269–271 [in Russian].

    Google Scholar 

  38. V. A. Petrovsky, Yu. V. Glukhov, A. E. Sukharev, et al., “Carbon Isotopic Composition of Diamonds (Monocrystal-Carbonado Association) as an Indicator of the Conditions of Diamond Formation,” Syktyvkar. Mineral. Sb., No. 34, 79–93 (2005).

  39. V. I. Silaev, V. A. Petrovsky, and A. E. Sukharev, Carbon Isotopic Heterogeneity in Mantle Derivatives, Including Carbonado (Geoprint, Syktyvkar, 2006) [in Russian].

    Google Scholar 

  40. R. N. Murogova, “Trimethyl Acetic Acid Source of Natural Diamonds Fuses,” in International Jubilee Conference Single Crystals and their Application in the XXI Century, Aleksandrov, Russia, 2004, (VNIISIMS, Aleksandrov, 2004), pp. 280–281.

    Google Scholar 

  41. V. I. Silaev, V. I. Rakin, S. N. Shanina, et al., “Mineralogy of Crystalline Calcium Formate,” Ural. Geol. Zh., No. 4, 107–123 (2005).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. A. Petrovsky.

Additional information

Original Russian Text © V.A. Petrovsky, V.I. Silaev, A.E. Sukharev, S.N. Shanina, M. Martins, J. Karfunkel, 2008, published in Geokhimiya, 2008, No. 7, pp. 748–765.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Petrovsky, V.A., Silaev, V.I., Sukharev, A.E. et al. Fluid phases in carbonado and their genetic significance. Geochem. Int. 46, 693–710 (2008). https://doi.org/10.1134/S0016702908070045

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702908070045

Keywords

Navigation