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Ionic Liquids—New Gas Chromatographic Phases with Unique Properties. A Review

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Abstract

A necessary and the most difficult element in the study of many chemical processes is a reliable chemical analysis of both the initial reagents and the products of their transformation. One of the most common methods for such analysis is capillary gas chromatography, which, unfortunately, has some limitations. The limitations include, for example, the low thermal stability of high polarity stationary liquid phases (SLPs). A way to overcome this limitation is the use of ionic liquids (ILs) as SLPs. In this review, we focus on the use of liquid phases based on ILs with cations of various chemical classes. The properties of such SLPs are considered from the point of view of their possible chromatographic selectivity, and examples of the use of columns with ILs for solving specific analytical problems are given. The properties of currently available commercial columns where ILs are used as the SLPs are discussed.

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Funding

The work was supported by the Ministry of Science and Higher Education in the framework of the State assignment of the Institute of Catalysis, SB RAS (project no. AAAA-А21-121011390053-4).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. V. Shashkov, V. N. Sidelnikov &  V. N. Parmon

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    M. V. Shashkov & V. N. Sidelnikov

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Shashkov, M.V., Sidelnikov, V.N. & Parmon, V.N. Ionic Liquids—New Gas Chromatographic Phases with Unique Properties. A Review. Dokl Phys Chem 508, 1–16 (2023). https://doi.org/10.1134/S0012501623600018

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