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Mass spectral evaluation of column bleeding for imidazolium-based ionic liquids as GC liquid phases

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Abstract

Mass spectra were obtained to evaluate the use of numerous single-cation and dicationic ionic liquids as stationary liquid phases in GC/MS at high temperature. Background mass spectra and product ion mass spectra of several ions in the background spectrum were obtained. Fragmentation mechanisms were propounded, including the detailed fragmentation pathway of the 1,2-dimethyl-3-propylimidazole cation. The relation between temperature and the main signals in the mass spectra of ILs was studied.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis SB RAS, pr. Lavrentieva 5, 630090, Novosibirsk, Russia

    M. V. Shashkov & V. N. Sidelnikov

Authors
  1. M. V. Shashkov
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  2. V. N. Sidelnikov
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Correspondence to M. V. Shashkov.

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Shashkov, M.V., Sidelnikov, V.N. Mass spectral evaluation of column bleeding for imidazolium-based ionic liquids as GC liquid phases. Anal Bioanal Chem 403, 2673–2682 (2012). https://doi.org/10.1007/s00216-012-6020-9

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  • DOI: https://doi.org/10.1007/s00216-012-6020-9

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