Abstract
The topology and stability of steady states of a continuous stirred-tank reactor were studied for a liquid–liquid heterogeneous system in which an exothermic reaction occurs. It was shown that the heat of the reaction, its energy barrier, and the mass transfer rate strongly affect the type of the structure of the emerging steady state, and the topological pattern changes through a series of degenerate steady states.
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REFERENCES
Frank-Kamenetskii, D.A., Diffuziya i teploperedacha v khimicheskoi kinetike (Diffusion and Heat Transfer in Chemical Kinetics), Moscow: Nauka, 1987.
Bykov, V.I. and Tsybenova, S.B., Nelineinye modeli khimicheskoi kinetiki (Nonlinear Models of Chemical Kinetics), Moscow: KRASAND, 2018.
Vaganov, D.A., Samoilenko, N.G., and Abramov, V.G., Chem. Eng. Sci., 1978, vol. 33, no. 8, pp. 1131–1140.
Andronov, A.A., Vitt, A.A., and Khaikin, S.E., Teoriya kolebanii (Qscillation Theory), Moscow: Nauka, 1981.
Arnol’d, V.I., Afraimovich, V.S., Il’yashenko, Yu.S., and Shil’nikov, L.P., Itogi Nauki Tekh., Ser. Sovr. Probl. Mat. Fundam. Naprvl., 1986, vol. 5, pp. 5–218.
Orlova, E.Yu., Khimiya i tekhnologiya brizantnykh vzryvchatykh veshchestv (Chemistry and Technology of High Explosives), Leningrad: Khimiya, 1973.
Mezhov, E.A., Ekstraktsiya aminami i chetvertichnymi ammonievymi osnovaniyami (Extraction with Amines and Quaternary Ammonium Bases), Moscow: Energoatomizdat, 1999.
Abramov, V.G. and Merzhanov, A.G., Teor. Osnovy Khim. Tekhnol., 1975, vol. 9, no. 6, pp. 863–869.
Perlmutter, D.D., Stability of Chemical Reactors, Englewood Cliffs: Prentice-Hall, 1972. Translated under the title Ustoichivost’ khimicheskikh reaktorov, Leningrad: Khimiya, 1976.
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This work was performed under the State Assignment (subject nos. 0089–2014–0032, 0089–2015–0224, 0089–2014–0017, and 0082–2016–0011).
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Translated by V. Glyanchenko
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Samoilenko, N.G., Shatunova, E.N., Shkadinskii, K.G. et al. Types of Steady States of a Continuous Stirred-Tank Reactor: Liquid–Liquid Heterogeneous System. Dokl Phys Chem 486, 73–76 (2019). https://doi.org/10.1134/S0012501619050038
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DOI: https://doi.org/10.1134/S0012501619050038