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Steady States of a Plug Flow Reactor Operating on a Heterogeneous Liquid−Liquid System

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
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Abstract

A plug flow reactor operating on a heterogeneous liquid−liquid system in which an exothermic bimolecular reaction takes place is modeled. The effect of the main governing parameters (Peclet and Damkheler numbers and a dimensionless parameter P characterizing mass transfer between the liquid phases) on the thermal modes of the reactor is examined. Depending on the values of these parameters, one or three steady states can be realized in the reactor. It is established that, with increasing parameter P, the region of multiplicity of steady states expands and shift toward lower values of the Damkohler number. The phenomenon of hysteresis is observed in the region of multiplicity of steady states.

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References

  1. Ya. B. Zel’dovich, Zh. Tekh. Fiz. 11 (6), 493 (1941).

    Google Scholar 

  2. R. C. Dougherty, J. R. Thygeson, and R. Hu, Chem. Eng. Commun. 126, 155 (1993).

    Article  CAS  Google Scholar 

  3. K. I. Alhumaizi and A. E. Abasaeed, Chem. Eng. Sci. 55, 3919 (2000).

    Article  CAS  Google Scholar 

  4. A. A. Kiss, C. S. Bildea, A. C. Dimian, and P. D. Iedema, Chem. Eng. Sci. 57, 535 (2002).

    Article  CAS  Google Scholar 

  5. G. H. Juncu, S. Bildea, and O. Florea, Chem. Eng. Sci. 49, 123 (1994).

    Article  CAS  Google Scholar 

  6. D. O. Borio, V. Bucala, and J. A. Porras, Chem. Eng. Sci. 50, 3115 (1995).

    Article  CAS  Google Scholar 

  7. E. V. Pisarenko, Usp. Khim. Khim. Tekhnol. 23 (1), 6 (2009).

    Google Scholar 

  8. A. A. Butakov, E. I. Maksimov, and K. G. Shkadinskii, Fiz. Goreniya Vzryva 14 (1), 62 (1978).

    CAS  Google Scholar 

  9. N. G. Samoilenko, E. N. Shatunova, V. A. Bostandzhiyan, and B. L. Korsunskii, Russ. J. Phys. Chem. B 11, 808 (2017).

    Article  CAS  Google Scholar 

  10. A. G. Merzhanov and A. K. Filonenko, Dokl. Akad. Nauk SSSR 152, 143 (1963).

    CAS  Google Scholar 

  11. R. M. Zaidel’ and Ya. B. Zel’dovich, Prikl. Mekh. Tekh. Fiz., No. 4, 27 (1962).

    Google Scholar 

  12. I. E. Sal’nikov and B. V. Vol’ter, Dokl. Akad. Nauk SSSR 152, 171 (1963).

    Google Scholar 

  13. A. A. Butakov and E. I. Maksimov, Dokl. Akad. Nauk SSSR 209, 643 (1973).

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    N. G. Samoilenko, E. N. Shatunova, V. A. Bostandzhiyan & B. L. Korsunskii

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    B. L. Korsunskii

  3. National Research Nuclear University MEPhI, Moscow, 115409, Russia

    B. L. Korsunskii

Authors
  1. N. G. Samoilenko
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  2. E. N. Shatunova
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  3. V. A. Bostandzhiyan
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  4. B. L. Korsunskii
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Corresponding author

Correspondence to B. L. Korsunskii.

Additional information

Original Russian Text © N.G. Samoilenko, E.N. Shatunova, V.A. Bostandzhiyan, B.L. Korsunskii, 2018, published in Khimicheskaya Fizika, 2018, Vol. 37, No. 3, pp. 8–12.

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Samoilenko, N.G., Shatunova, E.N., Bostandzhiyan, V.A. et al. Steady States of a Plug Flow Reactor Operating on a Heterogeneous Liquid−Liquid System. Russ. J. Phys. Chem. B 12, 196–199 (2018). https://doi.org/10.1134/S1990793118020100

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  • DOI: https://doi.org/10.1134/S1990793118020100

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