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Synthesis of Novel Composite Sorbents Based on Titanium, Calcium, and Magnesium Phosphates

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Abstract

Heterogeneous and mechanochemical syntheses of new materials based on titanium, calcium, and magnesium phosphates were developed for the first time. The products demonstrated high efficiency as sorbents for the removal of heavy metal cations and radionuclides from solutions. The joint action of the sorption components ensures high sorption capacity towards various cations over a wide pH range. The optimal conditions providing products with a specified phase composition were identified. The use of a solution of a phosphorus-containing agent and solid precursors taken in a stoichiometric ratio, together with mild hydrothermal conditions make it possible to minimize the amount of liquid waste. In the first step of the synthesis, precipitation of titanium phosphate and formation of the precursor needed for the second step (formation of calcium and magnesium phosphates) take place simultaneously. Thus, the synthesis protocol complies with the green chemistry principles.

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Funding

This study was supported by the Russian Science Foundation (project no. 23-23-00187).

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Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences”, 184209, Apatity, Russia

    N. V. Mudruk, M. V. Maslova &  A. I. Nikolaev

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  1. N. V. Mudruk
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  2. M. V. Maslova
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  3. A. I. Nikolaev
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Correspondence to N. V. Mudruk.

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Translated by Z. Svitanko

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Mudruk, N.V., Maslova, M.V. & Nikolaev, A.I. Synthesis of Novel Composite Sorbents Based on Titanium, Calcium, and Magnesium Phosphates. Dokl Chem 514, 42–49 (2024). https://doi.org/10.1134/S0012500824600020

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