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Magnetic susceptibility of quasi-one-dimensional Ising superantiferromagnets FeTAC and MCl2 · 2NC5H5 (M = Co, Fe): Approximation with L × ∞ and L × L × ∞ chain clusters

  • Order, Disorder, and Phase Transitions in Condensed Systems
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Abstract

The temperature dependence of the zero-field susceptibilities of 2D and 3D Ising lattices with anisotropic coupling is analyzed. Infinite 2D and 3D lattices are approximated, respectively, by ensembles of independent L × ∞ and L × L × ∞ chain clusters that are infinitely long in the strong-coupling (J) direction. This approach is used as a basis for a quantitative description of available experimental data on the magnetic susceptibilities of the 2D anisotropic Ising ferromagnet [(CH3)3NH]FeCl3 · 2H2O (FeTAC) and the quasi-one-dimensional 3D systems CoCl2 · 2NC5H5 and FeCl2 · 2NC5H5 in the entire experimental temperature range. A method is proposed for determining the relative interchain coupling strength J′/J from the maximum susceptibility value, which improves the accuracy of estimates for J′/J by more than an order of magnitude.

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  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    M. A. Yurishchev

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__________

Translated from Zhurnal Éksperimental’no\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\) i Teoretichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\) Fiziki, Vol. 128, No. 6, 2005, pp. 1227–1242.

Original Russian Text Copyright © 2005 by Yurishchev.

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Yurishchev, M.A. Magnetic susceptibility of quasi-one-dimensional Ising superantiferromagnets FeTAC and MCl2 · 2NC5H5 (M = Co, Fe): Approximation with L × ∞ and L × L × ∞ chain clusters. J. Exp. Theor. Phys. 101, 1077–1090 (2005). https://doi.org/10.1134/1.2163923

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