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Vibrational enhancement of the effective donor-acceptor coupling

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Abstract

This letter deals with a simple three-site model for charge transfer phenomena in a one-dimensional donor (D)-bridge (B)-acceptor (A) system coupled with vibrational dynamics of the B site. It is found that, in a certain range of parameters, the vibrational coupling leads to an enhancement of the effective donor-acceptor electronic coupling as a result of the formation of the polaron on the B site. This enhancement of the charge transfer efficiency is maximum at the resonance, where the effective energy of the fluctuating B site coincides with the donor (acceptor) energy.

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From Pis’ma v Zhurnal Éksperimental’noĭ i Teoreticheskoĭ Fiziki, Vol. 82, No. 6, 2005, pp. 407–411.

Original English Text Copyright © 2005 by Lazrek, Bicout, Jaziri, Kats.

The text was submitted by the authors in English.

A member of the editorial board of the journal from 1991 to 1997.

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Lazrek, M., Bicout, D.J., Jaziri, S. et al. Vibrational enhancement of the effective donor-acceptor coupling. Jetp Lett. 82, 366–370 (2005). https://doi.org/10.1134/1.2137374

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  • DOI: https://doi.org/10.1134/1.2137374

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