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Crystal structure of bis[diethylenetriamine-N′-(3-propionato)-N, N′,N″,O,O′]dicopper(II) Diperchlorate, [Cu2(4-Dtmp)2](ClO4)2

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Abstract

A complex of copper(II) with the diethylenetriaminemonopripionate ligand [Cu2(4-Dtmp)2](ClO4)2 (I) is synthesized and characterized using X-ray diffraction. The crystals of compound I are monoclinic, a = 7.740(2) Å, b = 19.199(3) Å, c = 8.449(2) Å, β = 91.61(2)°, Z = 2, and space group P21/n. The structural units of crystal I are centrosymmetric dimeric cations and statistically disordered ClO −4 anions. In the cation, the copper atom is coordinated by three N atoms [mean Cu-N, 2.01(1) Å] and two O atoms [Cu-O, 2.134(6) Å and 1.958(7) Å] of the pentadentate bridging-chelate Dtmp ligand, which occupy vertices of the trigonal bipyramid. The binuclear cations are linked via centrosymmetric pairs of hydrogen bonds into ribbons aligned parallel to the a axis of the crystal. The ClO −4 anions form columns in the same direction. In the crystal, the cationic ribbons and anionic columns alternate in a chessboard fashion.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. S. Antsyshkina, G. G. Sadikov & V. S. Sergienko

  2. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, pr. Franziska Skaryny 70, Minsk, 220072, Belarus

    A. L. Poznyak

Authors
  1. A. S. Antsyshkina
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  2. G. G. Sadikov
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  3. A. L. Poznyak
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  4. V. S. Sergienko
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Translated from Kristallografiya, Vol. 50, No. 3, 2005, pp. 450–454.

Original Russian Text Copyright © 2005 by Antsyshkina, Sadikov, Poznyak, Sergienko.

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Antsyshkina, A.S., Sadikov, G.G., Poznyak, A.L. et al. Crystal structure of bis[diethylenetriamine-N′-(3-propionato)-N, N′,N″,O,O′]dicopper(II) Diperchlorate, [Cu2(4-Dtmp)2](ClO4)2 . Crystallogr. Rep. 50, 406–409 (2005). https://doi.org/10.1134/1.1927599

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  • DOI: https://doi.org/10.1134/1.1927599

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