Abstract
The transport and thermoelectric properties of semiconducting rhenium silicide ReSi1.75 are comprehensively studied both experimentally and theoretically. Single-crystal samples of undoped and aluminumdoped ReSi1.75 are grown by floating-zone melting using optical heating. The temperature dependences of the resistivity, Hall coefficient, and Seebeck coefficient (thermoelectric power) are measured in the range 77–800 K. At room temperature, the charge-carrier concentration for the undoped rhenium silicide is 1019 cm−3 and the carrier mobility is 30 cm2/(V s). The theoretical study of the transport and thermoelectric properties includes ab initio calculation of the band structure; estimation of the carrier effective masses; simulation of the electron and hole mobility, taking into account classical scattering mechanisms; and calculation of the Seebeck coefficient. The results of the simulation and the experimental data are in good agreement.
Similar content being viewed by others
References
L. Ivanenko, H. Lange, and A. Heinrich, in Semiconducting Silicides, Ed. by V. E. Borisenko (Springer, Berlin, 2000), Chap. 5, p. 243.
C. A. Kleint, A. Heinrich, H. Griessmann, et al., in Proceedings of MRS Fall Meeting on Thermoelectric Materials, 1998 (Boston, USA, 1998); Mater. Res. Soc. Symp. Proc. 545, 165 (1999).
A. Heinrich, C. Kleint, H. Griessmann, et al., in Proceedings of XVIII International Conference on Thermoelectrics (Baltimore, USA, 1999), p. 161.
U. Gottlieb, B. Lambert-Andron, F. Nava, et al., J. Appl. Phys. 78, 3902 (1995).
I. Ali, P. Muret, and A. Haydar, Semicond. Sci. Technol. 16, 966 (2001).
L. Ivanenko, V. L. Shaposhnikov, A. B. Filonov, et al., Microelectron. Eng. 64(1–4), 225 (2002).
D. Souptel, G. Behr, L. Ivanenko, et al., J. Cryst. Growth 244, 296 (2002).
A. B. Filonov, D. B. Migas, V. L. Shaposhnikov, et al., Europhys. Lett. 46, 376 (1999); Microelectron. Eng. 50, 249 (2000).
P. Blaha, K. Schwarz, P. Sorantin, and S. B. Trickey, Comput. Phys. Commun. 59, 399 (1990).
V. L. Bonch-Bruevich and S. G. Kalashnikov, Physics of Semiconductors, 2nd ed. (Nauka, Moscow, 1990) [in Russian].
B. Ridley, Quantum Processes in Semiconductors (Clarendon, Oxford, 1982; Mir, Moscow, 1986), p. 143.
T. Siegrist, F. Hulliger, and G. Travaglini, J. Less-Common Met. 92, 119 (1983).
A. F. Ioffe, Physics of Semiconductors (Akad. Nauk SSSR, Leningrad, 1957; Infosearch, London, 1960).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 39, No. 4, 2005, pp. 419–423.
Original Russian Text Copyright © 2005 by Filonov, Krivosheev, Ivanenko, Behr, Schumann, Souptel, Borisenko.
Rights and permissions
About this article
Cite this article
Filonov, A.B., Krivosheev, A.E., Ivanenko, L.I. et al. The transport and thermoelectric properties of semiconducting rhenium silicide. Semiconductors 39, 395–399 (2005). https://doi.org/10.1134/1.1900250
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/1.1900250