Skip to main content
Log in

Fullerene single crystals as adsorbents of organic compounds

  • Conference. Amorphous, Vitreous, and Porous Semiconductors
  • Published:
Semiconductors Aims and scope Submit manuscript

Abstract

The results of investigations of the adsorption properties of fullerenes are presented. Fullerenes acting as adsorbents are compared with soot and activated carbon. From its adsorption properties, soot is similar to activated carbon. Fullerenes do not manifest themselves in the composition of soot material. As an independent adsorbent, fullerenes are considerably more effective than activated carbon. Possible mechanisms of fullerene adsorption are discussed. It is concluded that the adsorptivity of fullerenes is realized mainly through dispersion interactions. Certain theoretical estimates are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. Smart, B. Eldridge, W. Reuter, et al., Chem. Phys. Lett. 188, 171 (1992).

    Article  ADS  Google Scholar 

  2. R. S. Ruoff, D. S. Tse, R. Malhorta, and D. C. Lorents, J. Phys. Chem. 97, 3379 (1993).

    Google Scholar 

  3. V. N. Bezmel’nitsyn, A. V. Eletskii, and M. V. Okun’, Usp. Fiz. Nauk 168, 1195 (1998) [Phys. Usp. 41, 1091 (1998)].

    Google Scholar 

  4. Concise Chemical Encyclopedia, Ed. by I. L. Knunyants (Sovetskaya Entsiklopediya, Moscow, 1961), Vol. 1.

    Google Scholar 

  5. V. B. Fenelonov, Porous Carbon (Inst. Kataliza Sib. Otd. Ross. Akad. Nauk, Novosibirsk, 1995).

    Google Scholar 

  6. V. I. Berezkin, Phys. Status Solidi B 226, 271 (2001).

    ADS  Google Scholar 

  7. H. von Kienle and E. Bader, Aktivkohle und Ihre Industrielle Anwendung (Enke, Stuttgart, 1980; Khimiya, Moscow, 1984).

    Google Scholar 

  8. Production and Properties of Carbon Blacks, Ed. by V. F. Surovikin (Zap.-Sib. Knizh. Izd., Omsk, 1972).

    Google Scholar 

  9. F. E. Keneman, O. P. Potapov, P. V. Ryabinin, and É. A. Sokolov, in Carbon Adsorbents and Their Application in Industry, Ed. by T. G. Plachenov (Nauka, Moscow, 1983), p. 84.

    Google Scholar 

  10. A. D. Smirnov, Sorption Purification of Water (Khimiya, Leningrad, 1982).

    Google Scholar 

  11. Q.-M. Zhang, J.-Y. Yi, and J. Bernholc, Phys. Rev. Lett. 66, 2633 (1991).

    ADS  Google Scholar 

  12. M. S. Dresselhaus and G. Dresselhaus, Adv. Phys. 30, 139 (1981).

    Article  ADS  Google Scholar 

  13. O. Gunnarson, Rev. Mod. Phys. 69, 575 (1997).

    ADS  Google Scholar 

  14. L. Pauling, General Chemistry (Freeman, San Francisco, 1958; Mir, Moscow, 1964).

    Google Scholar 

  15. H. S. Chen, A. R. Kortan, R. C. Haddon, and D. A. Fleming, J. Phys. Chem. 96, 1016 (1992).

    Google Scholar 

  16. V. A. Rabinovich and Z. Ya. Khavin, Concise Chemical Handbook (Khimiya, Leningrad, 1977).

    Google Scholar 

  17. A. Cheng and M. L. Klein, Phys. Rev. B 45, 1889 (1992).

    ADS  Google Scholar 

  18. W. I. F. David, R. M. Iberson, J. C. Matthewman, et al., Nature 353, 147 (1991).

    Article  ADS  Google Scholar 

  19. E. Burgos, E. Halac, and H. Bonadeo, Phys. Rev. B 49, 15544 (1994).

  20. A. V. Eletskii and B. M. Smirnov, Usp. Fiz. Nauk 165, 977 (1995) [Phys. Usp. 38, 935 (1995)].

    Google Scholar 

  21. R. T. Morrison and R. M. Boyd, Organic Chemistry (Allyn and Bacon, Boston, 1970; Mir, Moscow, 1974).

    Google Scholar 

  22. A. Cheng and M. L. Klein, J. Phys. Chem. 95, 6750 (1991).

    Google Scholar 

  23. L. A. Girifalco, J. Phys. Chem. 96, 858 (1992).

    Article  Google Scholar 

  24. W. A. Steele, The Interaction of Gases with Solid Surfaces (Pergamon, New York, 1974).

    Google Scholar 

  25. S. Saito and A. Oshiyama, Phys. Rev. Lett. 66, 2637 (1991).

    Article  ADS  Google Scholar 

  26. Activated Carbon: A Catalog, Ed. by S. L. Glushakov, V. V. Konopleva, and N. G. Lyubchenko (Pravda, Cherkassy, 1990).

    Google Scholar 

  27. A. Dabrowski, Adv. Colloid Interface Sci. 93, 135 (2001).

    Article  Google Scholar 

  28. P. J. Wheatley, The Determination of Molecular Structure, 2nd ed. (Clarendon Press, Oxford, 1968; Mir, Moscow, 1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 37, No. 7, 2003, pp. 802–810.

Original Russian Text Copyright © 2003 by Berezkin, Viktorovski\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{\imath } \), Vul’, Golubev, Petrova, Khoroshko.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berezkin, V.I., Viktorovskii, I.V., Vul’, A.Y. et al. Fullerene single crystals as adsorbents of organic compounds. Semiconductors 37, 775–783 (2003). https://doi.org/10.1134/1.1592849

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.1592849

Keywords

Navigation