Abstract
The results of investigations of the adsorption properties of fullerenes are presented. Fullerenes acting as adsorbents are compared with soot and activated carbon. From its adsorption properties, soot is similar to activated carbon. Fullerenes do not manifest themselves in the composition of soot material. As an independent adsorbent, fullerenes are considerably more effective than activated carbon. Possible mechanisms of fullerene adsorption are discussed. It is concluded that the adsorptivity of fullerenes is realized mainly through dispersion interactions. Certain theoretical estimates are presented.
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References
C. Smart, B. Eldridge, W. Reuter, et al., Chem. Phys. Lett. 188, 171 (1992).
R. S. Ruoff, D. S. Tse, R. Malhorta, and D. C. Lorents, J. Phys. Chem. 97, 3379 (1993).
V. N. Bezmel’nitsyn, A. V. Eletskii, and M. V. Okun’, Usp. Fiz. Nauk 168, 1195 (1998) [Phys. Usp. 41, 1091 (1998)].
Concise Chemical Encyclopedia, Ed. by I. L. Knunyants (Sovetskaya Entsiklopediya, Moscow, 1961), Vol. 1.
V. B. Fenelonov, Porous Carbon (Inst. Kataliza Sib. Otd. Ross. Akad. Nauk, Novosibirsk, 1995).
V. I. Berezkin, Phys. Status Solidi B 226, 271 (2001).
H. von Kienle and E. Bader, Aktivkohle und Ihre Industrielle Anwendung (Enke, Stuttgart, 1980; Khimiya, Moscow, 1984).
Production and Properties of Carbon Blacks, Ed. by V. F. Surovikin (Zap.-Sib. Knizh. Izd., Omsk, 1972).
F. E. Keneman, O. P. Potapov, P. V. Ryabinin, and É. A. Sokolov, in Carbon Adsorbents and Their Application in Industry, Ed. by T. G. Plachenov (Nauka, Moscow, 1983), p. 84.
A. D. Smirnov, Sorption Purification of Water (Khimiya, Leningrad, 1982).
Q.-M. Zhang, J.-Y. Yi, and J. Bernholc, Phys. Rev. Lett. 66, 2633 (1991).
M. S. Dresselhaus and G. Dresselhaus, Adv. Phys. 30, 139 (1981).
O. Gunnarson, Rev. Mod. Phys. 69, 575 (1997).
L. Pauling, General Chemistry (Freeman, San Francisco, 1958; Mir, Moscow, 1964).
H. S. Chen, A. R. Kortan, R. C. Haddon, and D. A. Fleming, J. Phys. Chem. 96, 1016 (1992).
V. A. Rabinovich and Z. Ya. Khavin, Concise Chemical Handbook (Khimiya, Leningrad, 1977).
A. Cheng and M. L. Klein, Phys. Rev. B 45, 1889 (1992).
W. I. F. David, R. M. Iberson, J. C. Matthewman, et al., Nature 353, 147 (1991).
E. Burgos, E. Halac, and H. Bonadeo, Phys. Rev. B 49, 15544 (1994).
A. V. Eletskii and B. M. Smirnov, Usp. Fiz. Nauk 165, 977 (1995) [Phys. Usp. 38, 935 (1995)].
R. T. Morrison and R. M. Boyd, Organic Chemistry (Allyn and Bacon, Boston, 1970; Mir, Moscow, 1974).
A. Cheng and M. L. Klein, J. Phys. Chem. 95, 6750 (1991).
L. A. Girifalco, J. Phys. Chem. 96, 858 (1992).
W. A. Steele, The Interaction of Gases with Solid Surfaces (Pergamon, New York, 1974).
S. Saito and A. Oshiyama, Phys. Rev. Lett. 66, 2637 (1991).
Activated Carbon: A Catalog, Ed. by S. L. Glushakov, V. V. Konopleva, and N. G. Lyubchenko (Pravda, Cherkassy, 1990).
A. Dabrowski, Adv. Colloid Interface Sci. 93, 135 (2001).
P. J. Wheatley, The Determination of Molecular Structure, 2nd ed. (Clarendon Press, Oxford, 1968; Mir, Moscow, 1970).
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Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 37, No. 7, 2003, pp. 802–810.
Original Russian Text Copyright © 2003 by Berezkin, Viktorovski\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{\imath } \), Vul’, Golubev, Petrova, Khoroshko.
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Berezkin, V.I., Viktorovskii, I.V., Vul’, A.Y. et al. Fullerene single crystals as adsorbents of organic compounds. Semiconductors 37, 775–783 (2003). https://doi.org/10.1134/1.1592849
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DOI: https://doi.org/10.1134/1.1592849