Abstract
Semi-insulating silicon carbide layers have been obtained by diffusion of vanadium into porous 4H-SiC. The diffusion was performed from a film deposited by cosputtering of silicon and vanadium, with the content of the latter equal to 20%. The diffusion profile of vanadium in porous silicon carbide has a complex structure with a fast diffusion coefficient of 7×10−15 cm2/s. The activation energy of the resistivity of vanadium-diffusion-doped porous SiC layers is 1.45 eV. The resistivity of vanadium-doped semi-insulating layers is 5×1011 Ω cm at 500 K, which exceeds the resistivity of undoped porous SiC by two orders of magnitude. The results obtained indicate that porous SiC is a promising material for semi-insulating substrates in device structures based on wide-bandgap semiconductors.
Similar content being viewed by others
References
H. McD. Hobgood, R. C. Glass, G. Augustine, et al., Appl. Phys. Lett. 66, 1364 (1995).
S. A. Reshanov, Diamond Relat. Mater. 9, 480 (2000).
T. S. Sudarshan, G. Gradinaru, G. Korony, et al., Diamond Relat. Mater. 6, 1392 (1997).
A. A. Lebedev, Fiz. Tekh. Poluprovodn. (St. Petersburg) 33, 129 (1999) [Semiconductors 33, 107 (1999)].
S. A. Reshanov and V. P. Rastegaev, Diamond Relat. Mater. 10, 2035 (2001).
T. Kimoto, T. Nakajima, H. Matsunami, et al., Appl. Phys. Lett. 69, 1113 (1996).
A. Edwards, D. N. Dwight, M. V. Rao, et al., J. Appl. Phys. 82, 4223 (1997).
M. Bickermann, B. M. Epelbaum, D. Hofmann, et al., J. Cryst. Growth 223, 211 (2001).
H. Yamanaka and M. Kamashiba, Jpn. J. Appl. Phys. 13, 1661 (1974).
M. Mynbaeva, S. E. Saddow, G. Melnychuk, et al., Appl. Phys. Lett. 78, 117 (2001).
J. E. Spanier, G. T. Dunne, L. B. Rowland, and I. P. Hermann, Appl. Phys. Lett. 76, 3879 (2000).
J. K. Jeong, M. Y. Um, H. J. Na, et al., Mater. Sci. Forum 389–393, 267 (2002).
M. Mynbaeva, A. Titkov, A. Kryzhanovski, et al., MRS Internet J. Nitride Semicond. Res. 4, 14 (1999).
A. O. Konstantinov, C. I. Harris, and E. Janzen, Appl. Phys. Lett. 65, 2699 (1994).
S. E. Saddow, M. Mynbaeva, and M. McMillan, in Silicon Carbide: Materials, Devices and Applications, Ed. by Z. C. Feng and J. H. Zhao; Ser.: Optoelectronic Properties of Semiconductors and Superlattices (2003) (in press).
V. A. Dmitriev and M. G. Spencer, in SiC Materials and Devices. Semiconductors and Semimetals (Academic, New York, 1998), Vol. 52, p. 61.
A. Ellison, B. Magnusson, C. Hemmingson, et al., Mater. Res. Soc. Symp. Proc. 640, H1.2 (2001).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 37, No. 5, 2003, pp. 612–615.
Original Russian Text Copyright © 2003 by Mynbaeva, Lavrent’ev, N. Kuznetsov, A. Kuznetsov, Mynbaev, Lebedev.
Rights and permissions
About this article
Cite this article
Mynbaeva, M.G., Lavrent’ev, A.A., Kuznetsov, N.I. et al. Semi-insulating silicon carbide layers obtained by diffusion of vanadium into porous 4H-SiC. Semiconductors 37, 594–597 (2003). https://doi.org/10.1134/1.1575367
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/1.1575367