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Absorption line spectrum of the C60Cl24 halofullerene

  • Fullerenes and Atomic Clusters
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Abstract

Optical spectra of the C60Cl24 halofullerene in the crystalline state, as well as of C60Cl24 matrixisolated molecules, were studied. In both cases, a rich line structure was revealed in absorption spectra in the energy region 1.5–3.0 eV. An energy diagram of the electronic levels of the molecule which are responsible for the observed optical transitions is proposed. The parameters of the geometrical structure of the C60Cl24 molecule were calculated under the assumption of its having T h symmetry. These data were used in a theoretical study of the embedment of the C60Cl24 molecule in a toluene crystal matrix, which leads to the formation of a fine spectral structure (an analog of the Shpol’ski\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) effect) observed experimentally in this study.

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Authors and Affiliations

  1. Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia

    B. S. Razbirin, A. N. Starukhin, A. V. Chugreev & A. S. Zgoda

  2. St. Petersburg State Institute of Fine Mechanics and Optics, ul. Sablinskaya 14, St. Petersburg, 197101, Russia

    V. P. Smirnov

  3. Konstantinov Institute of Nuclear Physics, Russian Academy of Sciences, Gatchina, Leningrad oblast, 188350, Russia

    Yu. S. Grushko & S. G. Kolesnik

  4. Université Libre de Bruxelles, Brussels, 1050, Belgium

    P. -F. Coheur, J. Liévin & R. Colin

Authors
  1. B. S. Razbirin
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  2. A. N. Starukhin
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  3. A. V. Chugreev
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  4. A. S. Zgoda
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  5. V. P. Smirnov
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  6. Yu. S. Grushko
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  7. S. G. Kolesnik
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  8. P. -F. Coheur
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  9. J. Liévin
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  10. R. Colin
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__________

Translated from Fizika Tverdogo Tela, Vol. 44, No. 11, 2002, pp. 2106–2111.

Original Russian Text Copyright © 2002 by Razbirin, Starukhin, Chugreev, Zgoda, Smirnov, Grushko, Kolesnik, Coheur, Liévin, Colin.

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Razbirin, B.S., Starukhin, A.N., Chugreev, A.V. et al. Absorption line spectrum of the C60Cl24 halofullerene. Phys. Solid State 44, 2204–2209 (2002). https://doi.org/10.1134/1.1521480

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  • DOI: https://doi.org/10.1134/1.1521480

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