Abstract
The evolution of the geometric characteristics introduced by Pauling and their dependence on the specific features of the structure and chemical bonds have been considered. The values of the covalent and van der Waals radii are given as well as their relationships and mutual transitions.
Similar content being viewed by others
References
R. W. F. Bader, in International Series of Monographs on Chemistry, Vol. 22: Atoms in Molecules: A Quantum Theory (Clarendon, Oxford, 1994), p. 438.
M. L. Huggins, Phys. Rev. 28, 1086 (1926).
L. Pauling and M. L. Huggins, Z. Kristallogr. 87, 205 (1934).
J. A. van Vechten and J. C. Phillips, Phys. Rev. B 2(6), 2160 (1970).
J.-M. Savariault and M. S. Lehman, J. Am. Chem. Soc. 102(4), 1298 (1980).
K. L. Kunze and M. B. Hall, J. Am. Chem. Soc. 108(17), 5122 (1986).
S. S. Batsanov, Experimental Principles of Structural Chemistry (Standarty, Moscow, 1986).
S. S. Batsanov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 467 (1989).
V. Schomaker and D. P. Stevenson, J. Am. Chem. Soc. 63(1), 37 (1941).
S. B. Zhang, M. L. Cohen, and J. C. Phillips, Phys. Rev. B 38(17), 12085 (1988).
R. T. Sanderson, J. Am. Chem. Soc. 105(8), 2259 (1983).
Y.-R. Luo and S. W. Benson, J. Phys. Chem. 93(21), 7333 (1989).
S. S. Batsanov, Zh. Neorg. Khim. 36(12), 3015 (1991).
M. O'Keeffe and N. E. Brese, J. Am. Chem. Soc. 113(9), 3226 (1991).
M. O'Keeffe and N. E. Brese, Acta Crystallogr., Sect. B: Struct. Sci. 48(2), 152 (1992).
R. J. Gillespie and I. Hargittai, The VSEPR Model of Molecular Geometry (Allyn and Bacon, Boston, 1990; Mir, Moscow, 1992).
S. S. Batsanov, Izv. Akad. Nauk, Ser. Khim., No. 12, 2349 (1995).
D. Bergman and J. Hinze, Angew. Chem. Int. Ed. Engl. 35, 150 (1996).
S. S. Batsanov, Zh. Neorg. Khim. 43(3), 501 (1998).
L. Pauling, The Nature of the Chemical Bond and the Structure of Molecules and Crystals (Cornell Univ. Press, Ithaca, 1939, 1st ed.; 1960, 3rd ed.).
L. Pauling, J. Am. Chem. Soc. 69(3), 542 (1947).
I. D. Brown and D. Altermatt, Acta Crystallogr., Sect. B: Struct. Sci. 41(4), 244 (1985).
H.-B. Bürgi and J. D. Dunitz, J. Am. Chem. Soc. 109(10), 2924 (1987).
S. S. Batsanov, J. Phys. Chem. Solids 53(2), 319 (1992).
S. S. Batsanov, J. Phys. Chem. Solids 58(3), 527 (1997).
N. L. Allinger, X. Zhou, and J. Bergsma, J. Mol. Struct.: THEOCHEM 312, 69 (1994).
S. S. Batsanov, Structural Refractometry (Vysshaya Shkola, Moscow, 1976).
J. Paolini, J. Comput. Chem. 11(10), 1160 (1990).
F. A. Cotton and R. A. Walton, Multiple Bonds between Metal Atoms (Clarendon, Oxford, 1993, 2nd ed.).
M. Magat, Z. Phys. Chem. Abt. B 16(1), 1 (1932).
E. Mack, J. Am. Chem. Soc. 54(8), 2141 (1932).
S. S. Batsanov, Neorg. Mater. 37(9), 1031 (2001).
S. S. Batsanov, J. Mol. Struct.: THEOCHEM 468, 151 (1999).
S. S. Batsanov, Zh. Neorg. Khim. 46(9), 1519 (2001).
H. A. Bent, Chem. Rev. 68(5), 587 (1968).
H.-B. Bürgi, Angew. Chem. 87(13), 461 (1975).
P. Pyykkö, Chem. Rev. 97(5), 597 (1997).
A. É. Masunov and P. M. Zorky, Zh. Strukt. Khim. 33(3), 105 (1992).
M. A. Porai-Koshits, G. A. Kukina, Yu. N. Shevchenko, and V. S. Sergienko, Koord. Khim. 22(2), 83 (1996).
L. G. Kuz'mina, Koord. Khim. 25(9), 643 (1999).
K. Takemura, S. Minomura, O. Shimomura, et al., Phys. Rev. B 26(2), 998 (1982).
W. H. Zachariasen, Acta Crystallogr. 16(5), 385 (1963).
H.-B. Bürgi, Inorg. Chem. 12(10), 2321 (1973).
E. Dubler and L. Linowski, Helv. Chim. Acta 58(8), 2064 (1975).
S. S. Batsanov, Zh. Fiz. Khim. 75(4), 754 (2001).
Author information
Authors and Affiliations
Additional information
Dedicated to the 100th anniversary of Linus Pauling
__________
Translated from Kristallografiya, Vol. 46, No. 6, 2001, pp. 972–978.
Original Russian Text Copyright © 2001 by Batsanov.
Rights and permissions
About this article
Cite this article
Batsanov, S.S. Development of Pauling's concepts of geometric characteristics of atoms. Crystallogr. Rep. 46, 891–897 (2001). https://doi.org/10.1134/1.1420814
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.1420814