Skip to main content
Log in

Development of Pauling's concepts of geometric characteristics of atoms

  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The evolution of the geometric characteristics introduced by Pauling and their dependence on the specific features of the structure and chemical bonds have been considered. The values of the covalent and van der Waals radii are given as well as their relationships and mutual transitions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. W. F. Bader, in International Series of Monographs on Chemistry, Vol. 22: Atoms in Molecules: A Quantum Theory (Clarendon, Oxford, 1994), p. 438.

    Google Scholar 

  2. M. L. Huggins, Phys. Rev. 28, 1086 (1926).

    Article  ADS  Google Scholar 

  3. L. Pauling and M. L. Huggins, Z. Kristallogr. 87, 205 (1934).

    Google Scholar 

  4. J. A. van Vechten and J. C. Phillips, Phys. Rev. B 2(6), 2160 (1970).

    ADS  Google Scholar 

  5. J.-M. Savariault and M. S. Lehman, J. Am. Chem. Soc. 102(4), 1298 (1980).

    Article  Google Scholar 

  6. K. L. Kunze and M. B. Hall, J. Am. Chem. Soc. 108(17), 5122 (1986).

    Article  Google Scholar 

  7. S. S. Batsanov, Experimental Principles of Structural Chemistry (Standarty, Moscow, 1986).

    Google Scholar 

  8. S. S. Batsanov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 467 (1989).

  9. V. Schomaker and D. P. Stevenson, J. Am. Chem. Soc. 63(1), 37 (1941).

    Article  Google Scholar 

  10. S. B. Zhang, M. L. Cohen, and J. C. Phillips, Phys. Rev. B 38(17), 12085 (1988).

    Article  ADS  Google Scholar 

  11. R. T. Sanderson, J. Am. Chem. Soc. 105(8), 2259 (1983).

    Article  MathSciNet  Google Scholar 

  12. Y.-R. Luo and S. W. Benson, J. Phys. Chem. 93(21), 7333 (1989).

    Article  Google Scholar 

  13. S. S. Batsanov, Zh. Neorg. Khim. 36(12), 3015 (1991).

    Google Scholar 

  14. M. O'Keeffe and N. E. Brese, J. Am. Chem. Soc. 113(9), 3226 (1991).

    Google Scholar 

  15. M. O'Keeffe and N. E. Brese, Acta Crystallogr., Sect. B: Struct. Sci. 48(2), 152 (1992).

    Article  Google Scholar 

  16. R. J. Gillespie and I. Hargittai, The VSEPR Model of Molecular Geometry (Allyn and Bacon, Boston, 1990; Mir, Moscow, 1992).

    Google Scholar 

  17. S. S. Batsanov, Izv. Akad. Nauk, Ser. Khim., No. 12, 2349 (1995).

  18. D. Bergman and J. Hinze, Angew. Chem. Int. Ed. Engl. 35, 150 (1996).

    Google Scholar 

  19. S. S. Batsanov, Zh. Neorg. Khim. 43(3), 501 (1998).

    Google Scholar 

  20. L. Pauling, The Nature of the Chemical Bond and the Structure of Molecules and Crystals (Cornell Univ. Press, Ithaca, 1939, 1st ed.; 1960, 3rd ed.).

    Google Scholar 

  21. L. Pauling, J. Am. Chem. Soc. 69(3), 542 (1947).

    Article  Google Scholar 

  22. I. D. Brown and D. Altermatt, Acta Crystallogr., Sect. B: Struct. Sci. 41(4), 244 (1985).

    Article  Google Scholar 

  23. H.-B. Bürgi and J. D. Dunitz, J. Am. Chem. Soc. 109(10), 2924 (1987).

    Google Scholar 

  24. S. S. Batsanov, J. Phys. Chem. Solids 53(2), 319 (1992).

    Google Scholar 

  25. S. S. Batsanov, J. Phys. Chem. Solids 58(3), 527 (1997).

    Google Scholar 

  26. N. L. Allinger, X. Zhou, and J. Bergsma, J. Mol. Struct.: THEOCHEM 312, 69 (1994).

    Google Scholar 

  27. S. S. Batsanov, Structural Refractometry (Vysshaya Shkola, Moscow, 1976).

    Google Scholar 

  28. J. Paolini, J. Comput. Chem. 11(10), 1160 (1990).

    Article  Google Scholar 

  29. F. A. Cotton and R. A. Walton, Multiple Bonds between Metal Atoms (Clarendon, Oxford, 1993, 2nd ed.).

    Google Scholar 

  30. M. Magat, Z. Phys. Chem. Abt. B 16(1), 1 (1932).

    MATH  Google Scholar 

  31. E. Mack, J. Am. Chem. Soc. 54(8), 2141 (1932).

    Google Scholar 

  32. S. S. Batsanov, Neorg. Mater. 37(9), 1031 (2001).

    Google Scholar 

  33. S. S. Batsanov, J. Mol. Struct.: THEOCHEM 468, 151 (1999).

    Article  Google Scholar 

  34. S. S. Batsanov, Zh. Neorg. Khim. 46(9), 1519 (2001).

    Google Scholar 

  35. H. A. Bent, Chem. Rev. 68(5), 587 (1968).

    Article  Google Scholar 

  36. H.-B. Bürgi, Angew. Chem. 87(13), 461 (1975).

    Google Scholar 

  37. P. Pyykkö, Chem. Rev. 97(5), 597 (1997).

    Google Scholar 

  38. A. É. Masunov and P. M. Zorky, Zh. Strukt. Khim. 33(3), 105 (1992).

    Google Scholar 

  39. M. A. Porai-Koshits, G. A. Kukina, Yu. N. Shevchenko, and V. S. Sergienko, Koord. Khim. 22(2), 83 (1996).

    Google Scholar 

  40. L. G. Kuz'mina, Koord. Khim. 25(9), 643 (1999).

    Google Scholar 

  41. K. Takemura, S. Minomura, O. Shimomura, et al., Phys. Rev. B 26(2), 998 (1982).

    Article  ADS  Google Scholar 

  42. W. H. Zachariasen, Acta Crystallogr. 16(5), 385 (1963).

    Google Scholar 

  43. H.-B. Bürgi, Inorg. Chem. 12(10), 2321 (1973).

    Google Scholar 

  44. E. Dubler and L. Linowski, Helv. Chim. Acta 58(8), 2064 (1975).

    Article  Google Scholar 

  45. S. S. Batsanov, Zh. Fiz. Khim. 75(4), 754 (2001).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Dedicated to the 100th anniversary of Linus Pauling

__________

Translated from Kristallografiya, Vol. 46, No. 6, 2001, pp. 972–978.

Original Russian Text Copyright © 2001 by Batsanov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Batsanov, S.S. Development of Pauling's concepts of geometric characteristics of atoms. Crystallogr. Rep. 46, 891–897 (2001). https://doi.org/10.1134/1.1420814

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.1420814

Keywords

Navigation