Abstract
Using vacuum deposition, phthalocyanine films at constant and variable angles of vapor incidence on a substrate were produced. In some experiments, substrates were placed in a magnetic field, which was oriented along the surface. Hydrogen phthalocyanine films were processed with iodine and methyl iodide vapors. The anisotropy of samples was studied by the zero single-wave ellipsometry. In the experiments, the analyzer axis was oriented in the plane of incidence or in the plane of a sample, and a search for the polarizer and analyzer angles of suppression as functions of the polar angle of a sample was carried out. It is shown that the experimental data can be classified on the basis of three models proposed for the structure of phthalocyanine films. An expression for the description of anisotropy of films described by the three models is presented, and a method for finding parameters of a model is described. It is anticipated that reverse problems in the study of anisotropic media by ellipsometry can be solved without determining elements of the reflection matrix.
Similar content being viewed by others
References
J. Simon and J.-J. Andre, Molecular Semiconductors (Springer-Verlag, Berlin, 1985; Mir, Moscow, 1988).
H. Lee, H. Tabata, T. Matsumoto, and T. Kawai, Jpn. J. Appl. Phys., Part 1 36, 5156 (1997).
Y. L. Pan, Y. J. Wu, L. B. Chen, et al., Appl. Phys. A A66, 569 (1998).
B. A. Nesterenko and A. V. Nabok, Teor. Éksp. Khim. 29(4), 291 (1993).
T. Takamura, M. Moijama, T. Komatsu, and Y. Shimojama, Jpn. J. Appl. Phys., Part 1 38(5A), 2928 (1999).
E. Iton, M. Kokubo, S. Shouriki, and M. Iwamoto, J. Appl. Phys. 83, 372 (1998).
M. Brinkman, S. Graff, C. Chaumont, and J.-J. Andre, J. Mater. Res. 14, 2162 (1999).
E. F. Reznikova, V. A. Nadolinny, P. P. Semjannikov, et al., Nucl. Instrum. Methods Phys. Res. A 405, 519 (1998).
K. Z. Ogorodnik, Opt. Spektrosk. 39, 396 (1975) [Opt. Spectrosc. 39, 223 (1975)].
T. V. Basova and B. A. Kolesov, Thin Solid Films 325, 140 (1998).
M. K. Debe and D. R. Field, J. Vac. Sci. Technol. A 9, 1265 (1991).
M. K. Debe, J. Vac. Sci. Technol. A 10, 2816 (1992).
B. M. Ayupov, T. V. Basova, S. A. Prokhorova, and I. K. Igumenov, Poverkhnost’, No. 10, 110 (1997).
B. M. Ayupov and S. A. Prokhorova, Avtometriya, No. 2, 53 (1998).
J. M. Warman, P. G. Schouten, G. H. Gelink, and M. P. de Haas, Chem. Phys. 212, 183 (1996).
A. Yu. Tronin, Prib. Tekh. Éksp., No. 6, 123 (1981).
A. Yu. Tronin, Kristallografiya 34, 383 (1989) [Sov. Phys. Crystallogr. 34, 228 (1989)].
F. I. Fedorov and V. V. Filippov, Reflection and Refraction of Light by Transparent Crystals (Nauka i tekhnika, Minsk, 1976).
B. M. Ayupov, Optik (Stuttgart) 109(4), 145 (1998).
F. I. Filippov, A. Yu. Tronin, and A. F. Konstantinova, Kristallografiya 39, 360 (1994) [Crystallogr. Rep. 39, 313 (1994)].
R. M. A. Azzam and N. M. Bashara, J. Opt. Soc. Am. 62, 222 (1972).
I. M. Minkov, Opt. Spektrosk. 37, 309 (1974).
Author information
Authors and Affiliations
Additional information
__________
Translated from Optika i Spektroskopiya, Vol. 90, No. 3, 2001, pp. 509–514.
Original Russian Text Copyright © 2001 by Ayupov, Prokhorova.
Rights and permissions
About this article
Cite this article
Ayupov, B.M., Prokhorova, S.A. Optical anisotropy of phthalocyanine films. Opt. Spectrosc. 90, 446–451 (2001). https://doi.org/10.1134/1.1358458
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.1358458