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Temperature-dependent nepheloxetic shift of the 5 D 0→7 F 0 luminescence line of a Eu3+ ion in a superionic Na5Y(:Eu)Si4O12 single crystal

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Abstract

A decrease in the wavelength of the 5 D 0→7 F 0 luminescence line of a Eu3+ ion in a single crystal of the superionic conductor Na5Y(:Eu)Si4O12 is observed as a consequence of raising the temperature. The effect is interpreted as the result of a change in the distribution of mobile Na+ cations in the second coordination sphere of the luminescing rare-earth ion.

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Authors and Affiliations

  1. A. F. Ioffe Physicotechnical Institute, Russian Academy of Sciences, 194021, St. Petersburg, Russia

    M. E. Kompan & G. B. Venus

Authors
  1. M. E. Kompan
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  2. G. B. Venus
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Fiz. Tverd. Tela (St. Petersburg) 39, 1997–2000 (November 1997)

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Kompan, M.E., Venus, G.B. Temperature-dependent nepheloxetic shift of the 5 D 0→7 F 0 luminescence line of a Eu3+ ion in a superionic Na5Y(:Eu)Si4O12 single crystal. Phys. Solid State 39, 1786–1788 (1997). https://doi.org/10.1134/1.1130173

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  • DOI: https://doi.org/10.1134/1.1130173

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