Abstract
The motion of 221Fr and 213Bi in Actinide Resin, Dowex 50×8, and AMP-PAN sorbents in the course of continuous separation of these radionuclides from the parent 225Ac adsorbed on Actinide Resin was studied with the aim of obtaining chromatographic data for the development of a 225Ac/213Bi generator based on separation and decay of the intermediate 221Fr. A model describing the concentration of the daughter radionuclides as a function of the elution time and position in the volume of the chromatographic system was suggested. The distribution coefficients k′ of Fr and Bi on the above sorbents were determined experimentally.
Similar content being viewed by others
References
Strelow, F.W.E., Anal. Chem., 1960, vol. 32, no. 9, pp. 1185–1188.
Strelow, F.W.E., Rethemeyer, R., and Bothma, C.J.C., Anal. Chem., 1965, vol. 37, no. 1, pp. 106–111.
Tsubota, H., Bull. Chem. Soc. Jpn., 1963, vol. 36, no. 8, pp. 1038–1043.
Lilova, O.M. and Preobrazhenskii, B.K., Radiokhimiya, 1960, vol. 2, pp. 728–730.
Nelson, F., Michelson, D.C., Phillips, H.O., and Kraus, K.A., J. Chromatogr., 1965, vol. 20, pp. 107–121.
Nonaka, N., Sato, K., Higuchi, H., and Hamaguchi, H., Radioisotopes, 1976, vol. 25, no. 10, pp. 599–602.
Van Smith, J.R., Nature, 1958, vol. 181, pp. 1530–1531.
Inoue, Y., J. Inorg. Nucl. Chem., 1964, vol. 26, no. 12, pp. 2241–2253.
Huys, D. and Baetslé, L.H., J. Inorg. Nucl. Chem., 1964, vol. 26, no. 7, pp. 1329–1331.
Krtil, J., J. Inorg. Nucl. Chem., 1965, vol. 27, no. 1, pp. 233–236.
Voronina, A.V., Semenishchev, V.S., Nogovitsyna, E.V., and Betenekov, N.D., Radiochemistry, 2012, vol. 54, no. 1, pp. 73–78.
Voronina, A.V., Semenishchev, V.S., Nogovitsyna, E.V., and Betenekov, N.D., J. Radioanal. Nucl. Chem., 2013, vol. 298, pp. 67–75.
Sebesta, F. and Stefula, V., J. Radioanal. Nucl. Chem., 1990, vol. 140, no. 1, pp. 15–21.
Ermolaev, S.V. and Skasyrskaya, A.K., Abstracts of Papers, VIII Vserossiiskaya konferentsiya po radiokhimii “Radiokhimiya-2015” (VIII All-Russia Conf. on Radiochemistry “Radiochemistry-2015”), Zheleznogorsk, Krasnoyarsk krai, 2015, p. 442.
Morgenstern, A., Bruchertseifer, F., and Apostolidis, C., Curr. Radiopharm., 2011, vol. 4, pp. 295–305.
Ermolaev, S.V., Zhuikov, B.L., Kokhanyuk, V.M., et al., Radiochim. Acta, 2012, vol. 100, pp. 223–229.
National Nuclear Data Center, Brookhaven National Laboratory, USA, https://doi.org/www.nndc.bnl.gov/nudat2/.
Nelson, F., J. Chromatogr., 1964, vol. 16, pp. 538–540.
Bateman, H., Proc. Cambridge Phil. Soc., 1910, vol. 15, pp. 423–427.
Zhuikov, B.L., Kokhanyuk, V.M., Konyakhin, N.A., and Vincent, J., Nucl. Instr. Meth. Phys. Res. Sect. A, 1999, vol. 438, pp. 173–179.
Charged particle cross-section database for medical radioisotope production; diagnostic radioisotopes and monitor reactions: coordinated research project, IAEA-TECDOC-1211, Vienna: IAEA, 2001, ch. 4, https://doi.org/www-nds.iaea.org/medical.
Aliev, R.A., Ermolaev, S.V., Vasiliev, A.N., et al., Solvent Extr. Ion Exch., 2014, vol. 32, no. 5, pp. 468–477.
Sakodynskii, K.I., Brazhnikov, V.V., Volkov, S.A., et al., Analiticheskaya khromatografiya (Analytical Chromatography), Moscow: Khimiya, 1993.
Horwitz, E.P., Chiarizia, R., and Dietz, M.L., React. Funct. Polym., 1997, vol. 33, pp. 25–36.
Wu, C., Brechbiel, M.W., and Gansow, O.A., Radiochim. Acta, 1997, vol. 79, pp. 141–144.
Horwitz, E.P., Chiarizia, R., and Dietz, M.L., Solvent Extr. Ion Exch., 1992, vol. 10, pp. 313–336.
Horwitz, E.P., Dietz, M.L., Chiarizia, R., and Diamond, H., Anal. Chim. Acta, 1992, vol. 266, pp. 25–37.
Horwitz, E.P., Dietz, M.L., Chiarizia, R., et al., Anal. Chim. Acta, 1995, vol. 310, pp. 63–78.
Marhol, M., Ion Exchangers in Analytical Chemistry. Their Properties and Use in Inorganic Chemistry, Prague: Academia, 1982. Translated under the title Ionoobmenniiki v analiticheskoi khimii (Ion Exchangers in Analytical Chemistry), Moscow: Mir, 1985.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ermolaev, S.V., Skasyrskaya, A.K. Motion of Genetically Related 221Fr and 213Bi Radionuclides in a Chromatographic Medium. Radiochemistry 61, 44–54 (2019). https://doi.org/10.1134/S1066362219010077
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1066362219010077