Skip to main content
Log in

Luminescent Properties of Neodymium Acetylacetonate Introduced into Polymeric Matrixes in a Supercritical СО2 Medium

  • PHOTOCHEMISTRY AND MAGNETOCHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Phosphor polymers that exhibit luminescence in the blue region of the spectrum are produced by impregnating thermoplastic polymers with neodymium(III) acetylacetonate in a supercritical carbon dioxide medium. The spectral characteristics of the prepared systems are studied, and an interpretation of the observed change in the nature of luminescence is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. K. Kuriki, Y. Koike, and Y. Okamoto, Chem. Rev. 102, 2347 (2002).

    Article  CAS  PubMed  Google Scholar 

  2. H. Liang, Q. Zhang, Z. Zheng, et al., Opt. Lett. 29, 477 (2004).

    Article  CAS  PubMed  Google Scholar 

  3. J. Zubia and J. Arrue, Opt. Fiber Technol. 7, 101 (2001).

    Article  Google Scholar 

  4. S. Lian, C. Rong, D. Yin, et al., J. Phys. Chem. C 113, 6298 (2009).

    Article  CAS  Google Scholar 

  5. G. Zucchi, O. Mauru, P. Thuery, et al., Inorg. Chem. 47, 10398 (2008).

    Article  CAS  PubMed  Google Scholar 

  6. V. A. Vorob’ev, B. M. Sinel’nikov, V. D. Kreslavskii, et al., RF Patent No. 2007108564 (2010).

  7. S. Shuvaev, V. Utochnikova, L. Marciniak, et al., Dalton Trans. 43, 3121 (2014).

    Article  CAS  PubMed  Google Scholar 

  8. W. T. Carnall, P. R. Fields, and K. Rajnak, J. Chem. Phys. 49, 4424 (1968).

    Article  CAS  Google Scholar 

  9. A.-M. Fausto and J. V.-G. Maria, E. D.-G. Marta, Analyst 123, 151 (1998).

    Google Scholar 

  10. N. S. Poluektov, L. I. Kononenko, N. P. Efryushkina, and S. V. Bel’tyukova, Spectrophotometric and Luminescent Methods for the Determination of Lanthanides (Naukova Dumka, Kiev, 1989) [in Russian].

    Google Scholar 

  11. C. Huang, Rare Earth Coordination Chemistry (Wiley, New York, 2010).

    Book  Google Scholar 

  12. J.-C. G. Bunzli and S. V. Eliseeva, Springer Ser. Fluoresc. 7, 1–46 (2011).

    CAS  Google Scholar 

  13. I. V. Taidakov, Doctoral (Chem.) Dissertation (Peoples’ Friendship Univ. Russ, Moscow, 2015).

  14. H. F. Brito, O. L. Malta, M. C. F. C. Felinto, et al., J. Alloys Compd. 344, 294 (2002).

    Article  Google Scholar 

  15. S. V. Eliseeva and J.-C. G. Bunzli, Chem. Soc. Rev. 39, 1 (2009).

    Google Scholar 

  16. G. F. de Sa, O. L. Malta, C. de Mello Donega, et al., Coord. Chem. Rev. 196, 165 (2000).

    Article  CAS  Google Scholar 

  17. K. Binnemans, Chem. Rev. 109, 4283 (2009).

    Article  CAS  PubMed  Google Scholar 

  18. H.-G. Liu, F. Xiao, W.-S. Zhang, et al., J. Lumin. 114, 187 (2005).

    Article  CAS  Google Scholar 

  19. V. S. Marevtsev, L. S. Kol’tsova, A. V. Lyubimov, et al., Russ. Chem. Bull. 37, 2032 (1988).

    Article  Google Scholar 

  20. S. Z. Rogovina, A. B. Solov’eva, N. A. Aksenova, and A. A. Zharov, Polymer Sci., Ser. A 46, 238 (2004).

    Google Scholar 

  21. A. de Bettencourt-Dias, Dalton Trans., 2229 (2007).

  22. C. Du, L. Ma, Y. Xu, et al., Eur. Polym. J. 34, 23 (1998).

    Article  CAS  Google Scholar 

  23. D. Wang, J. Zhang, Q. Lin, et al., J. Mater. Chem. 13, 2279 (2003).

    Article  CAS  Google Scholar 

  24. V. I. Gerasimova, Yu. S. Zavorotnyi, A. O. Rybaltovskii, et al., Sverkhkrit. Fluidy Teor. Prakt. 5 (2), 56 (2010).

    Google Scholar 

  25. D. L. Tomasko, H. Li, D. Liu, et al., Ind. Eng. Chem. Res. 42, 6431 (2003).

    Article  CAS  Google Scholar 

  26. M. Polyakov and V. N. Bagratashvili, Ross. Khim. Zh. (Zh. Ob-va D. I. Mendeleeva) 43 (2), 93 (1999).

  27. N. N. Glagolev, A. B. Solov’eva, A. V. Kotova, V. T. Shashkova, B. I. Zapadinskii, N. L. Zaichenko, L. S. Kol’tsova, A. I. Shienok, P. S. Timashev, and V. N. Bagratashvili, Russ. J. Phys. Chem. A 83, 861 (2009).

    Article  CAS  Google Scholar 

  28. L. Winkless, R. H. C. Tan, Y. Zheng, et al., Appl. Phys. Lett. 89, 111115 (2006).

    Article  CAS  Google Scholar 

  29. A. S. Kopylov, V. I. Yusupov, A. V. Cherkasova, et al., Sverkhkrit. Fluidy Teor. Prakt., No. 2, 56 (2018).

  30. F. M. Gumerov, A. N. Sabiraznov, and G. I. Gumerova, Sub- and Supercritical Fluids in Polymer Processing (FEN, Kazan, 2000) [in Russian].

    Google Scholar 

  31. A. V. Kotova, N. N. Glagolev, I. A. Matveeva, A. V. Cherkasova, V. T. Shashkova, L. A. Pevtsova, B. I. Zapadinskii, A. B. Solov’eva, and V. N. Bagratashvili, Polymer Sci., Ser. A 52, 522 (2010).

    Article  Google Scholar 

  32. A. A. Ansari, R. Ilmi, and K. Iftikhar, J. Lumin. 132, 51 (2012).

    Article  CAS  Google Scholar 

  33. N. A. Aksenova, N. N. Glagolev, V. T. Shashkova, N. L. Zaichenko, L. S. Kol’tsova, A. I. Shienok, I. R. Mardaleishvili, P. S. Timashev, B. I. Zapadinskii, and A. B. Solov’eva, Russ. J. Phys. Chem. A 82, 1570 (2008).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was funded by a subsidy allocated to the Institute of Chemical Physics, Russian Academy of Sciences, as part of State Task no. 46.14, AAAA-A17-117-117032750202-6, topic no. 0082-2014-0006 “Developing Scientific Bases of Environmentally Friendly Technologies for the Production of Chemicals and Materials, Including Nanomaterials, Using Nontraditional Ways of Treating a Substance (Solid-phase Processes, Photochemistry, Supercritical fluids) and Fast Chemical and Physical Processes in Turbulent Flows.”

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. S. Kaplin.

Additional information

Translated by L. Mosina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kaplin, V.S., Kopylov, A.S., Ionov, D.S. et al. Luminescent Properties of Neodymium Acetylacetonate Introduced into Polymeric Matrixes in a Supercritical СО2 Medium. Russ. J. Phys. Chem. 93, 1598–1602 (2019). https://doi.org/10.1134/S0036024419080120

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024419080120

Keywords:

Navigation