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Ferromagnetic Resonance Study of Biogenic Ferrihydrite Nanoparticles: Spin-Glass State of Surface Spins

  • Condensed Matter
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Abstract

Ferrihydrite nanoparticles (2–3 nm in size), which are products of the vital activity of microorganisms, are studied by the ferromagnetic resonance method. The “core” of ferrihydrite particles is ordered antiferromagnetically, and the presence of defects leads to the appearance of an uncompensated magnetic moment in nanoparticles and the characteristic superparamagnetic behavior. It is established from the ferromagnetic resonance data that the field dependence of the frequency is described by the expression 2πν/γ = HR + HA(T=0)(1 − T/T*), where γ is the gyromagnetic ratio, HR is the resonance field, HA ≈ 7 kOe, and T* ≈ 50 K. The induced anisotropy HA is due to the spin-glass state of the near-surface regions.

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Funding

This work was supported by the Russian Foundation for Basic Research, project no. 18-02-40137.This work was supported by the Russian Foundation for Basic Research, by the Government of Krasnoyarsk krai, by the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic Resonance in Ferrihydrite Nanoparticles: Effects Associated with the Core-Shell Structure”), and by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3).

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Authors and Affiliations

  1. Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russia

    S. V. Stolyar, D. A. Balaev, A. I. Pankrats, R. N. Yaroslavtsev, D. A. Velikanov & R. S. Iskhakov

  2. Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russia

    S. V. Stolyar, V. P. Ladygina & R. N. Yaroslavtsev

  3. Siberian Federal University, Krasnoyarsk, 660041, Russia

    S. V. Stolyar, D. A. Balaev, A. I. Pankrats & R. N. Yaroslavtsev

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  1. S. V. Stolyar
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  2. D. A. Balaev
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  3. V. P. Ladygina
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  4. A. I. Pankrats
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  5. R. N. Yaroslavtsev
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  6. D. A. Velikanov
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  7. R. S. Iskhakov
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Correspondence to S. V. Stolyar.

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Russian Text © The Author(s), 2020, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2020, Vol. 111, No. 3, pp. 197–202.

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Stolyar, S.V., Balaev, D.A., Ladygina, V.P. et al. Ferromagnetic Resonance Study of Biogenic Ferrihydrite Nanoparticles: Spin-Glass State of Surface Spins. Jetp Lett. 111, 183–187 (2020). https://doi.org/10.1134/S0021364020030145

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  • DOI: https://doi.org/10.1134/S0021364020030145

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