Abstract
Half-metallicity recently predicted in the zigzag-edge graphene nanoribbons (ZGNRs) and the hydrogenated carbon nanotubes (CNTs) enables fully spin-polarized electric currents, providing a basis for carbon-based spintronics. In both carbon systems, the half-metallicity arises from the edge-localized electron states under an electric field, lowering the critical electric field Dc for the half-metallicity being an issue in recent works on ZGNRs. A properly chosen direction of the electric field alone has been predicted to significantly reduce Dc in the hydrogenated CNTs, which in this work turned out to be the case in narrow bilayer ZGNRs (biZGNRs). Here, our simple model based on the electrostatic potential difference between the edges predicts that for wide biZGNRs of width greater than ~2.0 nm (10 zigzag carbon chains), only one layer of the biZGNRs becomes half-metallic leaving the other layer insulating as confirmed by our density functional theory (DFT) calculations. The electric field-induced switching of the spin-polarized current path is believed to open a new route to graphene-based spintronics applications.
Similar content being viewed by others
Introduction
BiZGNRs with terminating hydrogen atoms will be referred to as n-biZGNRs, the number of zigzag carbon chains n giving the width of the ribbon1,2,3,4,5,6,7,8. BiZGNRs can be built in three different stacking forms: AA, ABα and ABβ7. In AA stacking, carbon atoms in a layer locate directly above the carbon atoms in the other layer. In AB stacking (Bernal stacking in graphite), there are two types of carbon atoms, i.e., the carbon atoms in a layer are positioned above the center of the hexagons of the other layer, defining a B-sublattice and those positioned right on top of the carbon atoms in the other layer, forming an A-sublattice8,9,10,11. The ABα and ABβ forms are discerned by their edge alignment patterns7,9,10,11. The ground state of the AA stacking has been shown to be a non-magnetic metal or an insulator with antiferromagnetic inter- and intra-layer spin alignments6,7,12, while that of the ABα stacking is known to be a non-magnetic insulator9,10,12, or an insulating state with antiferromagnetic inter- and intra-layer spin alignments7. In our DFT calculations without considering van der Waals forces, ABβ stacking has an insulating ground state with antiferromagnetic intralayer and ferromagnetic interlayer spin alignments (see Fig. 1), while both AA and ABα stacking forms prefer non-magnetic states9,10. The spin alignment in the ABβ stacking is similar to that in single-layer ZGNRs13,14,15,16. Studies of biZGNRs have mostly aimed at imparting metallic properties by chemical doping and controlling the interlayer distance6,17,18. Because of the opposite spin orientations at opposite edges in the ABβ stacking form of biZGNRs, a transversal electric field causes an electrostatic potential difference between the edge states and thus between the opposite spin channels, which led us to investigate the electric field-induced half-metallicity in the system.
A simple model for an electrostatic potential difference between edges can be introduced for the ABβ stacking form of biZGNRs5,6. Due to the interlayer interaction, the electron states localized at the edge carbon atoms in the A-sublattice are expected to have higher energies than those in the B-sublattice6. The energy level shifts of the band edges of the energy bands, occupied by the edge-localized electrons, under an electric field D tilted at an angle θ from the x-axis can be expressed in terms of the electrostatic potential energy (see Fig. 1). For the spin channels for which the band gap closes (red spins in Fig. 2).
w, l and δx are the nanoribbon width, the interlayer distance and the lateral shift between the layers, respectively. The charge density localized at the edge carbon atoms is given as e/Ce. E and U are the energy levels of the band edges in the absence and in the presence of electric fields, respectively, with E1 < E2 < EF < E3 < E4 (see Fig. 2). The energy gaps U(LB)-U(RA) and U(LB)-U(RB) are smaller than the other two gaps. While U(LB)-U(RA) = E3-E2 is smaller than U(LB)-U(RB) = E3-E1 in the absence of an electric field, the electric field-induced energy level shift leading to reduction of the band gap in U(LB)-U(RB) may be greater than that in U(LB)-U(RA). From the two gaps, the electric field required for the band gap closure can be obtained as
Dc1 and Dc2 correspond to the band gap closure in a layer and between layers, respectively, the smaller of the two being the critical electric field Dc for a band gap closure in the biZGNRs.
When Dc = Dc2, half-metallicity occurs between the two layers. On the other hand, when Dc = Dc1, only one of the layers becomes half-metallic leaving the other insulating, which would happen in wide enough biZGNRs. In this case, inversion of the electric field direction would lead to a band gap closure in the opposite spin channel, giving rise to a switching between the half-metallic and the insulating layers. Thus, our model predicts a layer-selective half-metallicity in wide enough biZGNRs and allows one to switch the path of the spin current by switching the electric field direction.
The layer-selectivity predicted by the model was confirmed by the calculations of the projected density of states (PDOS) for the edge carbon atoms in biZGNRs. Fig. 3 shows the PDOS in the upper and lower layers of 12-biZGNRs with electric fields applied along the x-axis. Only the PDOS of the edge carbon atoms is shown in Fig. 3, the PDOS near the Fermi level of the carbon atoms in the middle of the biZGNRs being an order of magnitude smaller than those of the edge carbon atoms. With increasing electric field, the band gap decreases in a spin channel (in red) and increases in the opposite spin channel (in blue), band gap closure occurring only in the lower layer [Fig. 3b,c]. Thus, the electric field-induced half-metallicity would occur in the lower layer only, leaving the upper layer insulating. Upon further increasing the electric field, band gap closure occurs in the upper layer as well as in the lower layer [Fig. 3d]. In other words, the layer-selective half-metallicity only occurs within a certain electric field, as confirmed by DFT calculations employing higher electric fields. When the electric field direction was reversed, the band gap was shown to close in the opposite spin channel. Thus, half-metallicity would occur only in the upper layer leaving the lower layer insulating, confirming layer-selective half-metallicity as predicted by the model above. It is to be noted that the layer-selective half-metallicity was identified only in wide n-biZGNRs with n ≥ 10.
Figure 4a to c show the band structures of a 6-biZGNR at various electric fields and tilt angles. Under an electric field applied along the x-axis, the spatial separation between the two spin channels leads to energy level shifts of opposite signs for them giving rise to half-metallicity (Fig. 4b). The electric field direction dependence of the electric field required for the half-metallicity, predicted by the model discussed above, was also elucidated by our DFT calculations (Fig. 4c). The Dc(θ) were obtained from the band edges of the valence and conduction bands in n-biZGNRs as a function of n (Fig. 4d). The angle θM of minimum Dc(θ) is nonzero for n < 10, decreasing with increasing n and finally becoming zero at n = 10, for which the layer-selective half-metallicity sets in. Fig. 4d indicates that the angle dependence of Dc is described well by our simple model introduced above. The critical electric field Dc(θM) for half-metallicity is shown to be inversely proportional to the nanoribbon width (Fig. 4e).
Our work employing a simple model based on the electrostatic potential difference between the edge carbon atoms and density functional theory calculations shows that layer-selective half-metallicity can be obtained in wide enough bilayer nanoribbons by applying electric fields. Besides, the half-metallic layer may be switched by reversing the field direction, enabling control of the spin-polarized electric current path. Thus, our results may be instrumental in opening a new field of spintronic applications utilizing carbon-based nanomaterials.
Methods
A SIESTA version 3.2 package was employed for the DFT calculation19,20. This code adopts a localized linear combination of numerical atomic-orbital basis sets for the description of valence electrons and norm-conserving nonlocal pseudopotentials for the atomic core. The wave function is expanded with a double-ζ polarized (DZP) basis set. For the exchange-correlation potential, a generalized gradient approximation (GGA) of Perdew-Burke-Ernzerhof (PBE) form was used21. An energy cutoff of 210 Ry and k-point of 1 × 1 × 15 mesh in a Monkhorst–Pack scheme were employed for total energy convergence better than 1 meV/atom. The density of states (DOS) and the related quantities were calculated with k points of 1 × 1 × 1000 mesh. The atomic coordinates were optimized by using conjugated gradients method with a maximum force tolerance of 0.01 eV/Å in the absence of an electric field. The lattice parameter was set to a = 2.45778 Å. To simulate the external electric field, a periodic sawtooth potential was used. The supercell has 1.5-nm vacuum spacing in the x-direction and 1-nm vacuum spacing in the y-direction to avoid any intercell interactions.
In DFT codes using plane wave base sets, graphene layers have been reported not to bind with a standard GGA functional, the repulsive force being overestimated22,23. However, DFT codes using localized atomic orbitals such as SIESTA have been reported to bind graphene layers with a standard GGA functional24,25. In fact, our DFT calculations gave a well optimized interlayer distance of ~3.4 Å with or without an electric field, the layers thus holding together.
Additional Information
How to cite this article: Jeon, G. W. et al. Layer-selective half-metallicity in bilayer graphene nanoribbons. Sci. Rep. 5, 9825; doi: 10.1038/srep09825 (2015).
References
Son, Y-W., Cohen, M. L. & Louie, S. G. Half-metallic graphene nanoribbon. Nature 444, 347–349 (2006).
Lee, K. W. & Lee, C. E. Half-metallic carbon nanotubes. Adv. Mater. 24, 2019–2023 (2012).
Kan, E., Li, Z., Yang, J. & Hou, J. G. Half-metallicity in edge-modified zigzag graphene nanoribbons. J. Am. Chem. Soc. 130, 4224–4225 (2008).
Wu, M., Wu, X. & Zeng, X. C. Exploration of half metallicity in edge-modified graphene nanoribbons. J. Phys. Chem. C. 114, 3937–3944 (2010).
Lee, K. W. & Lee, C. E. Significant reduction of the triggering electric field for half-metallicity in hydrogenated carbon nanotubes by optimized field direction. Curr. Appl. Phys. 13, 894–896 (2013).
Guo, Y., Guo, W. & Chen, C. Semiconducting to half-metallic to metallic Transition on spin-resolved zigzag bilayer graphene nanoribbons. J. Phys. Chem. C 114, 13098–13105 (2010).
Santos, H., Ayuela, A., Chico, L. & Artacho, E. Van der Waals interaction in magnetic bilayer graphene nanoribbons. Phys. Rev. B 85, 245430 (2012).
Le´on, C. & Latg´e, A. Half-metallicity study of graphene nanoribbon bilayers under external fields. Phys. Rev. B 88, 245446 (2013).
Sahu, B., Min, H., MacDonald, A. H. & Banerjee, S. K. Energy gaps, magnetism and electric-field effects in bilayer graphene nanoribbons. Phys. Rev. B 78, 045404 (2008).
Zhang, Y., Lu, X-L., Jiang, Y., Teng, B. & Lu, J-Q. Structural and magnetic instability of bilayer and trilayer zigzag graphene nanoribbons. J. Comput. Theor. Nanosci. 8, 2448–2453 (2011).
Lima, M. P., Fazzio, A. & da Silva, A. J. R. Edge effects in bilayer graphene nanoribbons: Ab initio total-energy density functional theory calculations. Phys. Rev. B 79, 153401 (2009).
Zhong, X., Pandey, R. & Karna, S. P. Stacking dependent electronic structure and transport in bilayer graphene nanoribbons. Carbon 50, 784–790 (2012).
Lee, H., Son, Y-W., Park, N., Han, S. & Yu, J. Magnetic ordering at the edges of graphitic fragments: Magnetic tail interactions between the edge-localized states. Phys. Rev. B 72, 174431 (2005).
Fujita, M., Wakabayashi, K., Nakada, K. & Kusakabe, K. Peculiar localized state at zigzag graphite edge. J. Phys. Soc. Jpn. 65, 1920–1923 (1996).
Nakada, K., Fujita, M., Dresselhaus, G. & Dresselhaus, M. S. Edge state in graphene ribbons: nanometer size effect and edge shape dependence. Phys. Rev. B 54, 17954–17961 (1996).
Wakabayashi, K., Fujita, M., Ajiki, H. & Sigrist, M. Electronic and magnetic properties of nanographite ribbons. Phys. Rev. B 59, 8271–8282 (1999).
Xu, B., Lu, Y. H., Sha, Z. D., Feng, Y. P. & Lin, J. Y. Coupling of magnetic edge states in Li-intercalated bilayer and multilayer zigzag graphene nanoribbons. EPL 94, 27007 (2011).
Paulla, K. K. & Farajian, A. A. Stacking stability, emergence of magnetization and electromechanical nanosensing in bilayer graphene nanoribbons. J. Phys.-Condens. Matter 25, 115303 (2013).
Sánchez-Portal, D., Ordejon, P., Artacho, E. & Soler, J. M. Density-functional method for very large systems with LCAO basis sets. Int. J. Quantum Chem. 65, 453–461 (1997).
Soler, J. M. et al. The SIESTA method for ab initio order-N materials simulation. J. Phys.-Condes. Matter 14, 2745–2779 (2002).
Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865–3868 (1996).
Hasegawa, M., Nishidate, K. & Iyetomi, H. Energetics of interlayer binding in graphite: The semiempirical approach revisited. Phys. Rev. B 76, 115424 (2007).
Lee, K., Murray, E. D., Kong, L. Z., Lundqvist, B. I. & Langreth, D. C. Higher-accuracy van der Waals density functional. Phys. Rev. B 82, 081101 (2010).
Birowska, M., Milowska, K. & Majewski, J. A. Van der Waals density functionals for graphene layers and graphite. Acta Phys. Pol. A 120, 845–848 (2010).
Mohan, B., Kumar, A. & Ahluwalia, P. K. A first principle study of interband transitions and electron energy loss in mono and bilayer graphene: Effect of external electric field. Physica E 44, 1670–1674 (2012).
Acknowledgements
This work was supported by the National Research Foundation of Korea (Project No. 2013057555, Proton Users Program 2014M2B2A4030835, 2015M1A7A1A01002234 and NRF-2010-0027963).
Author information
Authors and Affiliations
Contributions
K.W.L. initiated the study and contributed to the interpretation of the data. G.W.J. performed DFT calculations and analyzed data. C.E.L. supervised the project. G.W.J., K.W.L. and C.E.L. wrote the manuscript.
Ethics declarations
Competing interests
The authors declare no competing financial interests.
Rights and permissions
This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
About this article
Cite this article
Jeon, G., Lee, K. & Lee, C. Layer-selective half-metallicity in bilayer graphene nanoribbons. Sci Rep 5, 9825 (2015). https://doi.org/10.1038/srep09825
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/srep09825
- Springer Nature Limited
This article is cited by
-
Magnetization in CNT induced by nitrogen doping and enhanced by transversal electric field application
Journal of Materials Science (2022)