Charge carriers in metal halide perovskites seem to be only marginally affected by defect-related trap states. Filippo De Angelis and Annamaria Petrozza suggest that the key to this behaviour lies in the redox chemistry of halide defects.
References
Stranks, S. D. et al. Phys. Rev. Appl. 2, 034007 (2014).
Adinolfi, V. et al. Adv. Mater. 28, 3406–3410 (2016).
Yin, W.-J., Shi, T. & Yan, Y. Appl. Phys. Lett. 104, 063903 (2014).
Meggiolaro, D. et al. Energy Environ. Sci. 11, 702–713 (2018).
Du, M.-H. J. Phys. Chem. Lett. 6, 1461–1466 (2015).
Mosconi, E. & De Angelis, F. ACS Energy Lett. 1, 182–188 (2016).
Wehrenfennig, C., Liu, M., Snaith, H. J., Johnston, M. B. & Herz, L. M. APL Mater. 2, 081513 (2014).
Wu, X. et al. J. Am. Chem. Soc. 137, 2089–2096 (2015).
Leijtens, T. et al. Energy Environ. Sci. 9, 3472–3481 (2016).
Tress, W. et al. Energy Environ. Sci. 11, 151–165 (2018).
Zhang, W. et al. Nat. Commun. 6, 10030 (2015).
Meggiolaro, D., Mosconi, E. & De Angelis, F. ACS Energy Lett. 2794–2798 (2017).
Boschloo, G. & Hagfeldt, A. Acc. Chem. Res. 42, 1819–1826 (2009).
Son, D.-Y. et al. Nat. Energy 1, 16081 (2016).
McMeekin, D. P. et al. Science 351, 151–155 (2016).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
De Angelis, F., Petrozza, A. Clues from defect photochemistry. Nature Mater 17, 383–384 (2018). https://doi.org/10.1038/s41563-018-0069-6
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41563-018-0069-6
- Springer Nature Limited
This article is cited by
-
Photodoping through local charge carrier accumulation in alloyed hybrid perovskites for highly efficient luminescence
Nature Photonics (2020)
-
Metal halide perovskite nanostructures for optoelectronic applications and the study of physical properties
Nature Reviews Materials (2019)