Abstract
The synthesis of 2,5-dimethylfuran (DMF) from 5-hydroxymethylfurfural (HMF) is a highly attractive route to a renewable fuel. However, achieving high yields in this reaction is a substantial challenge. Here it is described how PtCo bimetallic nanoparticles with diameters of 3.6 ± 0.7 nm can solve this problem. Over PtCo catalysts the conversion of HMF was 100% within 10 min and the yield to DMF reached 98% after 2 h, which substantially exceeds the best results reported in the literature. Moreover, the synthetic method can be generalized to other bimetallic nanoparticles encapsulated in hollow carbon spheres.
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Acknowledgements
This work was conducted in the framework of the ERC Advanced Grant project ‘POLYCAT’, in addition it was financially supported by the cluster of excellence ‘TMFB’.
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F.S. and G-H.W. conceived and designed the experiments. G-H.W. performed the synthesis of materials. G-H.W. and J.H. performed the catalytic tests. F.H.R. and F.W. participated in analysis of the data. H-J.B. performed STEM measurements and data analysis. B.S. performed TEM measurements and data analysis. C.W. performed XPS measurements and data analysis. G-H.W. and F.S. wrote the manuscript. F.S. supervised the project. All authors discussed the results and commented on the manuscript.
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Wang, GH., Hilgert, J., Richter, F. et al. Platinum–cobalt bimetallic nanoparticles in hollow carbon nanospheres for hydrogenolysis of 5-hydroxymethylfurfural. Nature Mater 13, 293–300 (2014). https://doi.org/10.1038/nmat3872
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DOI: https://doi.org/10.1038/nmat3872
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