Empty liquids and equilibrium gels have so far been only theoretical possibilities, predicted for colloids with patchy interactions. But evidence of both has now been found in Laponite, a widely studied clay.
References
Bianchi, E., Largo, J., Tartaglia, P., Zaccarelli, E. & Sciortino, F. Phys. Rev. Lett. 97, 168301 (2006).
Glotzer, S. C. & Solomon, M. J. Nature Mater. 6, 557–562 (2007).
Hermans, T. M. et al. Nature Nanotech. 4, 721–726 (2009).
Pawar, A. B. & Kretzschmar, I. Langmuir 24, 355–358 (2008).
Hong, L., Cacciuto, A., Luijten, E. & Granick, S. Langmuir 24, 621–625 (2008).
Ruzicka, B. et al. Nature Mater. 10, 56–60 (2011).
van Olphen, H. Prog. Colloid Polym. Sci. 61, 46–53 (1976).
Lu, P. J. et al. Nature 453, 499–503 (2008).
Kutter, S., Hansen, J-P., Sprik, M. & Boek, E. J. Chem. Phys. 112, 311–322 (2000).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kegel, W., Lekkerkerker, H. Clay goes patchy. Nature Mater 10, 5–6 (2011). https://doi.org/10.1038/nmat2927
Published:
Issue Date:
DOI: https://doi.org/10.1038/nmat2927
- Springer Nature Limited
This article is cited by
-
Slow dynamics and equilibrium gelation in fractionated montmorillonite nanoplatelet dispersions
Colloid and Polymer Science (2019)
-
In-situ Observation of Hierarchical Self-Assembly Driven by Bicontinuous Gelation in Mixed Nanodisc Dispersions
Scientific Reports (2018)
-
Transition from glass- to gel-like states in clay at a liquid interface
Scientific Reports (2016)