The durability of glasses and minerals in water has traditionally been predicted using models that ignore the molecular details. Now the surface structure dynamics are shown to play an integral role in their aqueous corrosion.
References
Casey, W. H. & Bunker, B. Mineral–Water Interface Geochemistry (eds Hochella, M. F. & White, A. F.) Ch. 10, 397–424 (Reviews in Mineralogy 23, Mineralogical Society of America, 1990).
Cailleteau, C. et al. Nature Mater. 7, 978–983 (2008).
Casey, W. H., Westrich, H. R., Banfield, J. R., Ferruzzi, G. & Arnold, G. W. Nature 366, 253–256 (1993).
Bunker, B. C., Tallant, D. R., Headley, T. J., Turner, G. L. & Kirkpatrick, R. J. Phys. Chem. Glass. 29, 105–120 (1988).
Casey, W. H., Westrich, H. R., Arnold, G. W. & Banfield, J. F. Geochim. Cosmochim. Acta 53, 821–832 (1989).
Boudart, M. J. Phys. Chem. 80, 2869–2870 (1976).
Temkin, M. I. Int. Chem. Eng. 11, 709–717 (1971).
Casey, W. H. & Rustad, J. R. Annu. Rev. Earth Sci. 35, 21–46 (2007).
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Casey, W. Dynamics and durability. Nature Mater 7, 930–932 (2008). https://doi.org/10.1038/nmat2326
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DOI: https://doi.org/10.1038/nmat2326
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