Skip to main content
Log in

Use of Infra-red Spectroscopy to determine the Orientation of Pyridine sorbed on Montmorillonite

  • Letter
  • Published:

From Nature

View current issue Submit your manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

ORGANIC molecules sorbed on layer silicates generally adopt one single orientation. For those molecules for which the assignation of the absorption bands to the different vibrational modes has been well established, this association presents a favourable case for analysis by infra-red Spectroscopy. The orientation of the molecules can be inferred from the observed dichroism of specific absorption bands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Kline, C. H., and Turkevich, J., J. Chem. Phys., 12, 300 (1944).

    Article  ADS  CAS  Google Scholar 

  2. Corsin, L., Fax, B. J., and Lord, R. C., J. Chem. Phys., 21, 1170 (1953).

    Article  ADS  Google Scholar 

  3. Greene-Kelly, R., Trans. Faraday Soc., 51, 412 (1955).

    Article  CAS  Google Scholar 

  4. Cook, D., Canad. J. Chem., 39, 2009 (1961).

    Article  CAS  Google Scholar 

  5. Gill, N. S., Nuttall, R. H., Scaife, D. E., and Sharp, D. W. A., J. Inorg. Nucl. Chem., 18, 79 (1961).

    Article  CAS  Google Scholar 

  6. Swoboda, A. R., and Kunze, G. W., Clay and Clay Minerals, 13 (Pergamon Press, London, in the press).

  7. Greene-Kelly, R., Clay and Clay Minerals, 10, 469 (Pergamon Press, London, 1963).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

SERRATOSA, J. Use of Infra-red Spectroscopy to determine the Orientation of Pyridine sorbed on Montmorillonite. Nature 208, 679–681 (1965). https://doi.org/10.1038/208679a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/208679a0

  • Springer Nature Limited

Navigation