Abstract
AROMATIC nitrosobenzenes are dimeric in the solid state, but the nature of the link between the two halves of the molecule is not known1. An attempt to solve the problem has been made using the methods of X-ray analysis on crystals of para-chloro- and para-bromo-nitrosobenzene. The chlorine or bromine atom was introduced to make possible the solution of the structure by the heavy-atom method.
Similar content being viewed by others
References
Hammick, D. Ll., Illingworth, W. S., Edwards, W. A. M., and Ewbank, E. E., J. Chem. Soc., 3105 (1931); Plant, S. G. P., ibid., 3111 (1931).
Clews, C. J. B., and Cochran, W., Acta Cryst., 2, 54 (1949).
Robertson, J. M., J. Chem. Soc., 232 (1939).
Cox, E. G., Jeffrey, G. A., and Stadler, H. P., J. Chem. Soc., 1783 (1949).
Giguere, P. A., and Schomaker, V., J. Amer. Chem. Soc., 68, 2025 (1943).
Jerslev, B., Acta Cryst., 1, 21 (1948).
Lister, M. W., and Sutton, L. E., Trans. Farad. Soc., 35, 495 (1939).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
DARWIN, C., HODGKIN, D. Crystal Structure of the Dimer of para-Bromonitrosobenzene. Nature 166, 827–828 (1950). https://doi.org/10.1038/166827a0
Issue Date:
DOI: https://doi.org/10.1038/166827a0
- Springer Nature Limited
This article is cited by
-
Structural Analysis of Methyl-Substituted Nitrosobenzenes and Nitrosoanisoles
Journal of Chemical Crystallography (2014)
-
On the dimerization process of nitroso compounds
Theoretica Chimica Acta (1994)
-
The electronic spectra of the anion radicals of substituted benzenes
Theoretica Chimica Acta (1966)
-
�ber das CF3NO und einige seiner Reaktionen
Die Naturwissenschaften (1953)