Abstract
IN a recent communication1 we indicated the importance of planarity of dye molecules for the absorption of light and for photographic sensitizing. A further survey of cyanine dyes has shown this to be general; moreover, we find that dyes capable of planar form, but having strain on bond angles, show a negative temperature coefficient of absorption- in solution. Increase of rotational-vibrational energy in the molecule overcomes the strain and relaxes the structure to a non-planar form. The activation heat can be equated to the potential energy of strain which is removed.
Similar content being viewed by others
References
NATURE, 145, 386 (1940).
Sheppard, S. E., Lambert, R. H., and Walker, R. D., J. Chem. Phys., 7 265, 426 (1939).
Sheppard, S. E., Vanselow, W., and Happ, G. P., J. Phys. Chem., 44, 411 (1940).
Kameyama, N., and Fukumoto, T., J. Soc. Chem. Ind. (Japan), 42, 489 (1939).
von Hippel, A., Z. Phys., 67, 707; 68, 309 (1931); 75, 145 (1932).
Eggert, J., and Biltz, M., Trans. Farad. Soc., 34, 892 (1938).
Jelley, E. E., NATURE, 139, 631 (1937).
Scheibe, G., Kolloid. Z., 82, 1 (1938).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
SHEPPARD, S., LAMBERT, R. & WALKER, R. Optical Sensitizing of Silver Halides by Dyes. Nature 145, 969–970 (1940). https://doi.org/10.1038/145969a0
Issue Date:
DOI: https://doi.org/10.1038/145969a0
- Springer Nature Limited