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Environmentally Benign Carbonylation Reaction: Palladium-Catalyzed Hydroxycarbonylation of Aryl Halides and Benzyl Chloride Derivatives in Ionic Liquid Media

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Abstract

Palladium-catalyzed hydroxycarbonylations of aryl halides and benzyl chloride derivatives proceeded in ionic liquid media (l-butyl-3-methylimidazolium hexafluorophosphate (1), tetrafluoroborate (2) and Aliquat®336 (3)). The palladium-catalyst/mixture could be recycled, after separation of the product by extraction with water. The use of ionic liquid media greatly increased the yield of benzoic acid in hydroxycarbonylation.

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Authors and Affiliations

  1. National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5, Tsukuba, Ibaraki, 305-8565, Japan

    Eiichiro Mizushima, Teruyuki Hayashi & Masato Tanaka

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  1. Eiichiro Mizushima
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  2. Teruyuki Hayashi
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  3. Masato Tanaka
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Mizushima, E., Hayashi, T. & Tanaka, M. Environmentally Benign Carbonylation Reaction: Palladium-Catalyzed Hydroxycarbonylation of Aryl Halides and Benzyl Chloride Derivatives in Ionic Liquid Media. Topics in Catalysis 29, 163–166 (2004). https://doi.org/10.1023/B:TOCA.0000029798.75155.ff

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  • DOI: https://doi.org/10.1023/B:TOCA.0000029798.75155.ff

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