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Palladium-catalyzed aminocarbonylation of aryl iodides with amines: efficient access to bidentate amide directing groups

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Abstract

A new route to bidentate amide directing groups has been developed via the palladium(II)-catalyzed aminocarbonylation. Under atmospheric carbon monoxide pressure, using commercially available aryl iodides and aromatic amine derivatives as substrates, the three-component reaction proceeded smoothly to give the desired products in moderate-to-excellent yields with good functional-group compatibility.

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Notes

  1. For selected reviews on transition metals catalyzed C–H functionalization.

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Acknowledgements

We are grateful to the Key Science Research of Education Committee in Henan Province (19A150035), the Key Scientific and Technological Project of Henan Province (192102110222), the Program for Science & Technology Innovation Talents in Universities of Henan Province (14HASTIT016) and the Program of Science and Technology Innovation Talents of Henan Province (No. 2018JQ0011).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing, 163318, People’s Republic of China

    Yanqing Wang & Guoliang Mao

  2. Henan Engineering Laboratory of Green Synthesis for Pharmaceuticals, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, People’s Republic of China

    Tao Wang, Xiaosha Wang & Lantao Liu

  3. College of Chemistry, Zhengzhou University, Zhengzhou, 450001, People’s Republic of China

    Lantao Liu

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  1. Yanqing Wang
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  2. Tao Wang
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  3. Xiaosha Wang
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  4. Lantao Liu
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  5. Guoliang Mao
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Correspondence to Tao Wang or Guoliang Mao.

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Wang, Y., Wang, T., Wang, X. et al. Palladium-catalyzed aminocarbonylation of aryl iodides with amines: efficient access to bidentate amide directing groups. Transit Met Chem 46, 29–35 (2021). https://doi.org/10.1007/s11243-020-00418-4

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  • DOI: https://doi.org/10.1007/s11243-020-00418-4

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