Abstract
Complexes of the types VO(L)(R-deaH), VO(R-dea)(LH), and VO(L)(OGOH)[L = deprotonated form of N-(1-hydroxyethyl) naphthaldimine; R-dea = deprotonated form of a N-substituted diethanolamine, with R = H or Ph; G = CH2CH2, CHMeCHMe, CMe2CMe2, CHMeCH2CMe2, CMe2CH2CH2CMe2] have been prepared by the equimolar reactions of VO(OPri)3, LH2, and an appropriate diethanolamine or glycol in benzene. All of these coloured solid complexes have been characterised by elemental (C, H, N, and V) analyses and by spectroscopic (i.r., electronic, 1H-, 51V-n.m.r) studies. The relative lability of the hydroxy group(s) of N-(1-hydroxyethyl)naphthaldiamine, diethanolamine, and glycol has also been investigated.
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Ghadwal, R.S., Sharma, M., Singh, A. et al. Synthesis and Spectroscopic Characterisation of Six-Coordinate Complexes of Oxovanadium(V). Transition Metal Chemistry 29, 419–424 (2004). https://doi.org/10.1023/B:TMCH.0000027460.70418.98
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DOI: https://doi.org/10.1023/B:TMCH.0000027460.70418.98