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Oxovanadium(iv) cations in heterometallic and heteroligand complex formation

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Abstract

The formation of heterometallic oxovanadium(iv) diethylenetriaminepentaacetates with titanium(iii), chromium(iii), cobalt(ii), nickel(ii), and manganese(ii) cations in aqueous solutions was studied by spectrophotometry and pH-metry. The stabilizing influence of heterometallic chelation on an unstable oxidation state of Tiiii and the labilizing effect of oxovanadium(iv) cations on the coordination of Criii cations by the carboxylate ligand anions in the heterometallic complex were shown. The optimum conditions for the formation of the heterometallic dtpa complexes were selected and their thermodynamic stability was estimated. The states of the oxovanadium(iv) cations in the monoand heteroligand systems involving polyamine, polyaminopolycarboxylate, and alkylpolyphosphonate ligands were studied. Specific features of ligand coordination and formation of the mixed-ligand chelates were investigated. A variety of molecular compositions of complex oxovanadium(iv) oxyethylenediphosphonate particles formed in ranges of pH 2.2—3.0, 4.5—5.5, and 6.3—6.4 was found. The preferability of formation of polynuclear oxovanadium(iv) oxyethylidenediphosphonates, viz., binuclear particles with oxovanadium(iv) cation to ligand molar ratios of 2 : 1 and 2 : 5 and trinuclear particles with a molar ratio of components of 3 : 2, was shown.

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Authors and Affiliations

  1. Moscow State Regional Institute of Humanities, 22 ul. Zelenaya, 142611, Orekhovo-Zuevo, Moscow Region, Russian Federation

    T. V. Popova & V. A. Kiseleva

  2. Mari State University, 1 pl. Lenina, 424000, Ioshkar-Ola, Mari-El Republic, Russian Federation

    N. V. Shcheglova

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  1. T. V. Popova
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  2. N. V. Shcheglova
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  3. V. A. Kiseleva
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Correspondence to T. V. Popova.

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Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1857—1865, August, 2015.

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Popova, T.V., Shcheglova, N.V. & Kiseleva, V.A. Oxovanadium(iv) cations in heterometallic and heteroligand complex formation. Russ Chem Bull 64, 1857–1865 (2015). https://doi.org/10.1007/s11172-015-1084-2

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  • DOI: https://doi.org/10.1007/s11172-015-1084-2

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