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Kinetics of the Volume and Surface Reactions in the Phase-Transfer Catalytic Aminolysis of 4-Nitrophenyl Acetate

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Abstract

It was shown that a distribution-type kinetic model can be used to describe the mechanism of the phase-transfer catalytic aminolysis of 4-nitrophenyl acetate with potassium glycinate in chlorobenzene with 18-crown-6 as catalyst. A quantitative assessment was made of the contributions from the reactions in the volume and at the interface in the solid/liquid system.

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Vul., 83114 Donets'k, Ukraine

    L. N. Vakhitova, A. F. Popov, Ya. F. Burdina, V. A. Savelova & I. A. Belousova

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  1. L. N. Vakhitova
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  2. A. F. Popov
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  3. Ya. F. Burdina
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  4. V. A. Savelova
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  5. I. A. Belousova
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Vakhitova, L.N., Popov, A.F., Burdina, Y.F. et al. Kinetics of the Volume and Surface Reactions in the Phase-Transfer Catalytic Aminolysis of 4-Nitrophenyl Acetate. Theoretical and Experimental Chemistry 40, 226–233 (2004). https://doi.org/10.1023/B:THEC.0000041807.91332.45

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  • DOI: https://doi.org/10.1023/B:THEC.0000041807.91332.45

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