Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of Mixed-Ligand Ni(II) Complex of N-(1-Phenyl-3-methyl-4-benzylidene-5-pyrazolone) p-Nitrobezoylhydrazide and Pyridine

  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

A novel mixed-ligand nickel complex, [Ni(PMBP—PNH) (Py)3], [PMBP—PNH=N-(1-phenyl-3-methyl-4-benzylidene-5-pyrazolone) p-nitrobezoylhydrazide; Py = pyridine], has been synthesized by the hydrothermal method and characterized by elemental analysis, IR spectrum, thermal analysis, and single-crystal X-ray diffraction. The X-ray diffraction reveals that the nickel (II) ion in the title complex is in a slightly distorted octahedral arrangement of the ONO donor atoms of primary ligand PMBP-PNH and three N-donor atoms in the secondary ligand pyridine.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Uzoukwu, B. A.; Al-Juaid, S. S.; Hitchcock, P. B.; Smith, J. D. Polyhedron 1993, 12, 2719.

    Google Scholar 

  2. Louati, A.; Kuncaka, A.; Gross, M.; Haubtmann, C.; Bernard, M.; André, J. J.; Brunette, J. P. J. Organomet. Chem. 1995, 486, 95.

    Google Scholar 

  3. Rao, S. N.; Mishra, D. D.; Maurya, R. C.; Rao, N. N. Polyhedron 1997, 16, 1825.

    Google Scholar 

  4. Güven, A. L.; Kaniskan, N. J. Mol. Struct. (Theochem) 1999, 488, 125.

    Google Scholar 

  5. Pettinari, C.; Marchetti, F.; Santini, C.; Pettinari, R.; Drozdov, A.; Troyanov, S.; Battiston, G. A.; Gerbasi, R. Inorg. Chim. Acta 2001, 315, 88.

    Google Scholar 

  6. Kuznetsov, M. L.; Dement'ev, A. I.; Zhornik, V. V. J. Mol. Struct. (Theochem) 2001, 571, 45.

    Google Scholar 

  7. Uzoukwu, B. A.; Adiukwu, P. U.; Al-Juaid, S. S.; Hitchcock, P. B.; Smith, J. D. Inorg. Chim. Acta 1996, 250, 173.

    Google Scholar 

  8. Adhikari, N.; Chaudhuri, S.; Butcher, R. J.; Saha, N. Polyhedron 1999, 18, 1323.

    Google Scholar 

  9. Raman, N.; Kulandaisamy, A.; Shunmugasundaram, A.; Jeyasubramanian, K. Trans. Met. Chem. 2001, 26, 131.

    Google Scholar 

  10. Iskander, M. F.; Sayed, L.; Hefny, A. F. M.; Zayan, S. E. J. Inorg. Nucl. Chem. 1976, 38, 2209.

    Google Scholar 

  11. Havanur, G. H.; Mahale, V. B. Indian J. Chem. 1987, 26A, 1063.

    Google Scholar 

  12. Adams, H.; Fenton, D. E.; Minardi, G.; Mura, E.; Angelo, M. Inorg. Chem. Commun. 2000, 3, 4.

    Google Scholar 

  13. Yang, Z. Y.; Yang, R. D.; Li, F. S.; Yu, K. B. Polyhedron 2000, 19, 2599.

    Google Scholar 

  14. Liu, L.; Jia, D. Z.; Qiao, Y. M.; Yu, K. B. Huaxuexuebao 2001, 59, 1495.

    Google Scholar 

  15. Liu, L.; Jia, D. Z.; Ji, Y. L. Synth. React. Inorg. Met.-Org. Chem. 2002, 32, 739.

    Google Scholar 

  16. Liu, L.; Jia, D. Z.; Qiao, Y. M.; Ji, Y. L.; Yu, K. B. J. Chem. Crystallogr. 2002, 32, 255.

    Google Scholar 

  17. Ji, Y. L.; Liu, L.; Jia, D. Z.; Yu, K. B. Jiegouhuaxue 2002, 21, 553.

    Google Scholar 

  18. Liu, L.; Jia, D. Z.; Ji, Y. L.; Yu, K. B. J. Photochem. Photobiol. A Chem. 2003, 154, 117.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Applied Chemistry, Xinjiang University, Urumqi, 830046, People's Republic of China

    Li Zhang, Lang Liu & Dianzeng Jia

  2. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610012, People's Republic of China

    Kaibei Yu

Authors
  1. Li Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dianzeng Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kaibei Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dianzeng Jia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, L., Liu, L., Jia, D. et al. Synthesis and Crystal Structure of Mixed-Ligand Ni(II) Complex of N-(1-Phenyl-3-methyl-4-benzylidene-5-pyrazolone) p-Nitrobezoylhydrazide and Pyridine. Structural Chemistry 15, 327–331 (2004). https://doi.org/10.1023/B:STUC.0000026748.27516.2f

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:STUC.0000026748.27516.2f

Search

Navigation