Abstract
Previous magnetic and geochemical studies of stream sediments in the Northeast of Buenos Aires Province, in the Greater La Plata area, have revealed a high level of trace elements, especially lead and zinc. Continuing these preliminary works, new sampling sites were considered in order to improve and increase the magnetic mapping of this area. This part of the study focuses especially on the magnetic properties of sediments from a cross-city stream. Such stream receives a variable pollutant load from urban, industrial and diffuse sources.
Concentration-dependent magnetic parameters, magnetic carriers (para, anti and ferrimagnetic) and their features (e.g. softer or harder magnetic carrier, grain size distribution, etc.) have been calculated using magnetic measurements. According to magnetic parameters and heavy metal loads two main distinctive groups of sediment-cores are distinguished. The vertical distribution of sediments reveals a recent anthropogenic influence, possibly, belonging to the last 20-40 years.
Four out of all the magnetic parameters (magnetic susceptibility, anhysteric remanent magnetisation, S-ratio and κ ARM/κ) were chosen in order to investigate their relationship with contents of heavy metals. In all the cases, good positive correlations were obtained using linear regression. However, more significant correlation factors were achieved for grain size and magnetic feature-dependent parameters (κ ARM/κ and S-ratio) than for magnetic concentration-dependent parameters. Therefore, the κ ARM/κ and the S-ratio seem to be the most relevant magnetic parameters to describe the vertical and longitudinal distribution of heavy metals present in these stream sediments. The non-significant relationship between heavy metals and concentration-dependent parameters could be explained taking into account the discrimination of the two distinctive groups. The group belonging to the Coastal Plain shows a clear linear trend between heavy metals and magnetic susceptibility and anhysteric remanent magnetisation.
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Alzuet P., Gaspes E. and Ronco A., 1996. Mutagenecy of environmental samples from an industrialised area of the Río de La Plata Estuary using the Salmonella-Microsomal Assay. Environmental Toxicology and Water Quality, 11, 1231-1236.
Angulo E., 1996. The Tomlinson pollution load index applied to heavy metal “Mussel-Watch” data: a useful index to assess coastal pollution. Sci. Total. Environ.,187, 19-56.
Beckwith P., Ellis J., Revitt D. and Oldfield F., 1986. Heavy metal and magnetic relationships for urban source sediments. Phys. Earth Planet. Inter., 42, 67-75.
Bityukova L., Scholger R. and Birke M., 1999. Magnetic susceptibility as indicator of environmental pollution of soils in Tallin. Phys. Chem. Earth (A), 24, 829-835.
Bloemendal J., King J.K., Hall F.R. and Doh S.J., 1992. Rock magnetism of Late Neogene and Pleistocene deep-sea sediments: Relationship to sediment source, diagenetic processes and sediment lithology. J. Geophys. Res., 97, 4361-4375.
Cabral M.G., Hurtado M.A., Giménez J.E., Sánchez C.A., Muntz D. and da Silva M., 2002. Indices de afectación territorial en la planificación estratégica del partido de La Plata, Provincia de Buenos Aires, Argentina. V Jornadas Geológicas y Geofísicas Bonaerenses, 20 pp.
Chan L.S., Ng S.L., Davis A.M., Yim W.W.S. and Yeung C.H., 2001. Magnetic properties and heavy-metal contents of contaminated seabed sediments of Penny's bay, Hong Kong. Mar. Pollut. Bull., 42, 569-583.
Chaparro M.A.E., Gogorza C.S., Lavat A., Pazos S. and Sinito A.M., 2002. Preliminary results of magnetic characterisation of different soils in Tandil Region (Argentina) affected by the pollution of metallurgical factory. Eur. J. Env. Eng. Geophys., 7, 35-58.
Chaparro M.A.E, Bidegain J.C., Sinito A.M., Gogorza C.S., Jurado S., 2003. Preliminary results of magnetic measurements on stream sediments from Buenos Aires Province, Argentina. Stud.Geophys. Geod., 47, 53-77.
Chaparro M.A.E, Bidegain J.C., Sinito A.M., Gogorza C.S., Jurado S., 2004. Magnetic studies applied to different environments (soils and stream sediments) from a relatively polluted area in Buenos Aires Province, Argentina. Environ. Geol. 45, 654-664.
Dankers P.H.M., 1978. Magnetic Properties of Dispersed Natural Iron-Oxides of Known Grain-Size. PhD. thesis, State University of Utrecht, 142 pp.
Desenfant F., Petrovský E. and Rochette P., 2004. Magnetic signature of industrial pollution of stream sediments and correlation with heavy metals: case study from South France. Water, Air Soil Pollut., 152, 297-312.
Dunlop J. and Özdemir Ö., 1997. Rock Magnetism. Fundamentals and Frontiers. Cambridge University Press, Cambridge, 573 pp.
Ďurža O., 1999. Heavy contamination and magnetic susceptibility in soils around metallurgical plant. Phys. Chem. Earth (A), 24, 541-543.
EPA SW-846, 1986. Method 3050: Acid Digestion of Sediments, Sludges and Soils. Chapter 3: Metallic Analysis. Test Methods for Evaluating Solid Waste, Vol. 1, Section A, Part 1, Environmental Protection Agency, Washington D.C.
Fidalgo F. and Martinez O.R., 1983. Algunas características geomórficas dentro del Partido de La Plata (Pcia. de Buenos Aires). Asoc. Geol. Arg.,XXXVIII(2), 263-279.
Frink C.R., 1996. A perspective on metals in soils. J. Soil Contam., 5, 329-359.
Georgeaud V.M., Rochette P., Ambrosi J.P., Vandamme D. and Williamson D., 1997. Relationship between heavy metals and magnetic properties in a large polluted catchment: The Etang de Berre (South of France). Phys. Chem. Earth (A), 22, 211-214.
Goluchowska B.J. 2001. Some factors affecting an increase in magnetic susceptibility of cement dusts. J. Appl. Geophys., 48, 103-112.
Hanesch M. and Scholger R., 2002. Mapping of heavy metal loadings in soils by means of magnetic susceptibility measurements. Environ. Geol., 42, 857-870.
Heller F., Strzyszcz Z. and Magiera T., 1998. Magnetic record of industrial pollution in soils of Upper Silesia, Poland. J. Geophys. Res., 103, 17767-17774.
Hoffmann V, Knab M. and Appel E., 1999. Magnetic susceptibility of roadside pollution. J Geochem. Explor., 66, 313-326.
Hullet Jr. L.D., Weinberger A.J., Nothcutt K.J. and Ferguson M., 1980. Chemical species in fly ash from coal-burning power plants. Science, 210, 1356-1358.
Hunt A., Jones J. and Oldfield F., 1984. Magnetic measurements and heavy metals in atmospheric particulates of anthropogenic origin. Sci. Total Environ., 33, 129-139.
Jordanova D., Veneva L., Hoffmann V., 2003. Magnetic susceptibility screening of anthropogenic impact on the Danube River sediments in Northwestern Bulgaria-preliminary results. Stud.Geophys. Geod., 47, 403–418.
Kapička A., Jordanova N., Petrovský E. and Ustjak S., 2001. Effect of different soil conditions on magnetic parameters of power-plant fly ashes. J. Appl. Geophys., 48, 93-102.
King J., Banerjee S.K., Marvin J. and Özdemir Ö., 1982. A comparison of different magnetic methods for determining the relative grain size of magnetite in natural materials: Some results from lake sediments. Earth Planet. Sci. Lett., 59, 404-419.
Kruiver P.P., Dekkers M.J. and Heslop D., 2001. Quantification of magnetic coercivity components by the analysis of acquisition curves of isothermal remanent magnetisation. Earth Planet. Sci.Lett., 189, 269-276.
Kukier U., Fauziah Ishak C., Summer M.E. and Miller W.P., 2003. Composition and element solubility of magnetic and non-magnetic fly ash fractions. Environ. Pollut.,123, 255-266.
Lecoanet H., Léveque F. and Ambrosi J.-P., 2003. Combination of magnetic parameters: an efficient way to discriminate soil-contamination sources (south France). Environ. Pollut., 122, 229-234.
Legret M. and Pagotto C., 1999. Evaluation of pollutant loading in the runoff waters from a major rural highway. Sci. Total Environ., 235, 143-150.
Maher B.A., 1986. Characterisation of soils by mineral magnetic measurements. Phys. Earth Planet.Inter., 42, 76-92.
Maher B.A., Thompson R. and Hounslow M.W., 1999. Introduction. In: B.A. Thompson (Eds.), Quaternary Climates, Environments and Magnetism, Cambridge University Press, Cambridge, 1-48.
Manassero M., Camilion C. and Ronco A., 1998. Sedimentologia y geoquímica de metales pesados de fondo de arroyos de la vertiente del Río de La Plata. Provincia de Buenos Aires. VII Reunion Argentina de Sedimentología-Actas, 69-78.
Matzka J. and Maher B.A., 1999. Magnetic biomonitoring of roadside tree leaves: identification of spatial and temporal variations in vehicle-derived particulates. Atmos. Environ., 33, 4565-4569.
Peters C. and Dekkers M., 2003. Selected room temperature magnetic parameters as a function of mineralogy, concentration and grain size. Phys. Chem. Earth, 28, 659-667.
Peters C., Dekkers M.J. and Langereis C.G., 2002. Validation of mineral magnetic methods. Quaderni di Geofisica,26, 129-130.
Petrovský E., Kapička A., Zapletal K., Šebestová E., Spanilá T., Dekkers M.J. and Rochette P, 1998. Correlation between magnetic parameters and chemical composition of lake sediments from northern Bohemia-Preliminary study. Phys. Chem. Earth, 23, 1123-1126.
Petrovský E. and Elwood B.B., 1999. Magnetic monitoring of air, land and water pollution. In: B.A. Maher and R. Thompson (Eds.), Quaternary Climates, Environment and Magnetism, Cambridge University Press, Cambridge, 279-322.
Robertson D.J., Taylor K.G. abd Hoon S.R., 2003. Geochemical and mineral magnetic characterisation of urban sediment particulates, Manchester, UK. Appl. Geochem., 18, 269-282.
Ronco A., Sobrero C., Bulus Rosini G., Alzuet P. and Dutka B., 1995. Screening for sediment toxicity in the Río Santiago Basin: a baseline study. Environmental Toxicology and Water Quality, 10, 35-39.</del>
Ronco A., Camilon C. and Manassero M., 2001. Geochemistry of heavy metals in bottom sediments from streams of the western coast of the Río de la Plata estuary, Argentina. Environ.Geochem. Health, 23, 89-103.
SAGyP-INTA, 1989. Mapa de Suelos de la Provincia de Buenos Aires. Escala 1:500.000.
Proyecto PNUD ARG 85/019, Secretaria de Agricultura Ganaderia y Pesca, Buenos Aires, 527 pp.
Scholger R., 1998. Heavy pollution monitoring by magnetic susceptibility measurements applied to sediments of the river Mur (Styria, Austria). Eur. J. Environ. Eng. Geophys.,3, 25-37.
Strzyszcz Z., Magiera T and Heller F., 1996. The influence of industrial immisions on the magnetic susceptibility of soils in Upper Silesia. Stud. Geophys. Geod., 40, 276-286.
Strzyszcz Z. and Magiera T., 1998. Magnetic susceptibility and heavy metals contamination in soils of southern Poland. Phys. Chem. Earth, 23, 1127-1131.
Sutherland R.A., 2003. Lead in grain size fractions of road-deposited sediment. Environ. Pollut., 121, 229-237.
Tauxe L., 1993. Sedimentary records of relative paleointensity of the geomagnetic field: Theory and practice. Rev. Geophys., 31, 319-354.
Thompson R. and Oldfield F., 1986. Environmental Magnetism. Allen & Unwin, 225 pp.
Vassilev S.V., 1992. Phase mineralogy studies of solid waste products from coal burning at some Bulgarian thermoelectric power plants. Fuel, 71, 625-633.
Walkley A. and Black I.A., 1934. An examination of the method for determining soil organic matter and a proposed modification of the chromic acid titration method. Soil Sci., 37, 29-38.
Zhang W. and Yu L., 2002. Relationships between magnetic properties and heavy metals in intertidal sediments of the Yangtze Estuary, China. Quaderni di Geofisica,26, 195-197.
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Chaparro, M., Bidegain, J., Sinito, A. et al. Relevant Magnetic Parameters and Heavy Metals from Relatively Polluted Stream Sediments - Vertical and Longitudinal Distribution Along a Cross-City Stream in Buenos Aires Province, Argentina. Studia Geophysica et Geodaetica 48, 615–636 (2004). https://doi.org/10.1023/B:SGEG.0000037474.08544.8e
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DOI: https://doi.org/10.1023/B:SGEG.0000037474.08544.8e