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N-Chloro-N-(1,2,2,2-tetrachloro- and 1,2,2-trichloroethyl)- sulfonamides from N,N-Dichlorosulfonamides and 1,2-Polychloroethenes

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Abstract

N,N-Dichlorosulfonamides react with trichloroethylene and 1,2-dichloroethylene at a temperature not exceeding 20°C to afford unstable addition products, N-chloro-N-(1,2,2,2-tetrachloroethyl)- and N-chloro-N-(1,2,2-trichloroethyl)sulfonamides. The latter undergo elimination of chlorine on heating, irradiation, or prolonged storage to give the corresponding N-(2,2-di- or 2,2,2-trichloroethylidene)arene(or trifluoromethane)sulfonamides.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    E. V. Kondrashov, I. B. Rozentsveig, G. G. Levkovskaya & L. V. Kanitskaya

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  1. E. V. Kondrashov
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  2. I. B. Rozentsveig
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  3. G. G. Levkovskaya
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  4. L. V. Kanitskaya
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Kondrashov, E.V., Rozentsveig, I.B., Levkovskaya, G.G. et al. N-Chloro-N-(1,2,2,2-tetrachloro- and 1,2,2-trichloroethyl)- sulfonamides from N,N-Dichlorosulfonamides and 1,2-Polychloroethenes. Russian Journal of Organic Chemistry 39, 1418–1420 (2003). https://doi.org/10.1023/B:RUJO.0000010557.39998.2b

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  • DOI: https://doi.org/10.1023/B:RUJO.0000010557.39998.2b

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