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Phenols Reactions with 1,1-Difluorodichloroethene, 1,2-Di(fluorochloro)ethene, and Trifluorochloroethene

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Abstract

Phenols containing in the para-position of the benzene ring substituents of various electronic character add to 1,1-difluorodichloroethene in acetone in the presence of potassium hydroxide. A similar reaction with 1,2-di(fluorochloro)ethene occurs only in DMF or N,N-dimethylacetamide and is followed by hydrogen chloride elimination. Phenols with electron-donor substituents add to trifluorochloroethene in acetone in the presence of potassium hydroxide, the reaction of phenols with electron-acceptor substituents requires DMF as solvent.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, 02094, Ukraine

    M. M. Kremlev, A. I. Mushta & L. I. Moklyarchuk

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  1. M. M. Kremlev
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  2. A. I. Mushta
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  3. L. I. Moklyarchuk
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Kremlev, M.M., Mushta, A.I. & Moklyarchuk, L.I. Phenols Reactions with 1,1-Difluorodichloroethene, 1,2-Di(fluorochloro)ethene, and Trifluorochloroethene. Russian Journal of Organic Chemistry 39, 1125–1129 (2003). https://doi.org/10.1023/B:RUJO.0000010179.88527.27

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  • DOI: https://doi.org/10.1023/B:RUJO.0000010179.88527.27

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